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- W4290726875 abstract "Abstract Nanohybrid materials are designed to cover up the weaknesses of individual components. In this current work, an environment‐friendly synthesis was used to produce a cyan‐emitting copper nanocluster (Cu NC) with a quantum yield of 8.7 %. This negatively charged nanocluster was successfully used to make a nanohybrid with anatase titanium dioxide mesoporous nanoparticles having Lewis‐acidic pores. The nanohybrid formation was characterized by time‐correlated single‐photon counting studies (TCSPC), solid‐state UV‐visible absorption spectroscopy and valence band X‐ray photoelectron spectroscopy. A systematic increase of Cu NC loading on the TiO 2 showed an increase of current from a range of 10 −7 A (in native TiO 2 ) to 10 −4 A (1 : 10 Cu NC‐TiO 2 hybrid). Interestingly, the photocurrent response of TiO 2 also dramatically improved from 8.9×10 −3 mA to 4.1 mA in1 : 10 Cu NC−TiO 2 hybrid. Systematic variation of their weight ratio vividly demonstrated that 10 % w/w TiO 2 −Cu NC hybrid was the most effective current generator, keeping the semiconducting and photovoltaic nature intact. The increase in photocurrent can be attributed to the long‐lived electron‐hole separation in the nanohybrid system." @default.
- W4290726875 created "2022-08-09" @default.
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- W4290726875 date "2022-08-08" @default.
- W4290726875 modified "2023-10-16" @default.
- W4290726875 title "A Nanohybrid Containing Cyan‐Emitting Copper Nanoclusters and TiO<sub>2</sub> Nanoparticles: Tuning of Optoelectronic Properties" @default.
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- W4290726875 doi "https://doi.org/10.1002/slct.202201701" @default.
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