Matches in SemOpenAlex for { <https://semopenalex.org/work/W4291567125> ?p ?o ?g. }
- W4291567125 endingPage "10289" @default.
- W4291567125 startingPage "10262" @default.
- W4291567125 abstract "Alkynes occupy a prominent role as a coupling partner in the transition metal-catalysed directed C-H activation reactions. Due to low steric requirements and linear geometry, alkynes can effectively coordinate with metal d-orbitals. This makes alkynes one of the most successful coupling partners in terms of the number of useful transformations. Remarkably, by changing the reaction conditions and transition-metals from 5d to 3d, the pattern of reactivity of alkynes also changes. Due to the varied reactivity of alkynes, such as alkenylation, annulation, alkylation, and alkynylation, they have been extensively used for the synthesis of valuable organic molecules. Despite enormous explorations with alkynes, there are still a lot more possible ways by which they can be made to react with M-C bonds generated through C-H activation. Practically there is no limit for the creative use of this approach. In particular with the development of new high and low valent first-row metal catalysts, there is plenty of scope for this chemistry to evolve as one of the most explored areas of research in the coming years. Therefore, a highlight article about alkynes is both timely and useful for synthetic chemists working in this area. Herein, we have highlighted the diverse reactivity of alkynes with various transition metals (Ir, Rh, Ru, Pd, Mn, Fe, Co, Ni, Cu) and their applications, along with some of our thoughts on future prospects." @default.
- W4291567125 created "2022-08-15" @default.
- W4291567125 creator A5017868998 @default.
- W4291567125 creator A5021986629 @default.
- W4291567125 creator A5025766809 @default.
- W4291567125 creator A5026742129 @default.
- W4291567125 creator A5067800903 @default.
- W4291567125 creator A5074898838 @default.
- W4291567125 date "2022-01-01" @default.
- W4291567125 modified "2023-10-14" @default.
- W4291567125 title "Diverse reactivity of alkynes in C–H activation reactions" @default.
- W4291567125 cites W1964564850 @default.
- W4291567125 cites W1996892407 @default.
- W4291567125 cites W2020842445 @default.
- W4291567125 cites W2085247175 @default.
- W4291567125 cites W2094939276 @default.
- W4291567125 cites W2098478603 @default.
- W4291567125 cites W2162494517 @default.
- W4291567125 cites W2260216711 @default.
- W4291567125 cites W2289537353 @default.
- W4291567125 cites W2307160623 @default.
- W4291567125 cites W2320715866 @default.
- W4291567125 cites W2324983845 @default.
- W4291567125 cites W2329472798 @default.
- W4291567125 cites W2344135776 @default.
- W4291567125 cites W2460245280 @default.
- W4291567125 cites W2476721801 @default.
- W4291567125 cites W2499623768 @default.
- W4291567125 cites W2502352965 @default.
- W4291567125 cites W2510375492 @default.
- W4291567125 cites W2516651331 @default.
- W4291567125 cites W2518284621 @default.
- W4291567125 cites W2531397205 @default.
- W4291567125 cites W2581918531 @default.
- W4291567125 cites W2586347035 @default.
- W4291567125 cites W2586912622 @default.
- W4291567125 cites W2587649655 @default.
- W4291567125 cites W2610981781 @default.
- W4291567125 cites W2614366029 @default.
- W4291567125 cites W2724422844 @default.
- W4291567125 cites W2732259921 @default.
- W4291567125 cites W2735576679 @default.
- W4291567125 cites W2736176361 @default.
- W4291567125 cites W2743808049 @default.
- W4291567125 cites W2746458387 @default.
- W4291567125 cites W2754403859 @default.
- W4291567125 cites W2762852891 @default.
- W4291567125 cites W2768737175 @default.
- W4291567125 cites W2774819994 @default.
- W4291567125 cites W2777651827 @default.
- W4291567125 cites W2781102172 @default.
- W4291567125 cites W2783135639 @default.
- W4291567125 cites W2793428809 @default.
- W4291567125 cites W2795409314 @default.
- W4291567125 cites W2798036745 @default.
- W4291567125 cites W2800409626 @default.
- W4291567125 cites W2802789129 @default.
- W4291567125 cites W2803878515 @default.
- W4291567125 cites W2805964693 @default.
- W4291567125 cites W2883408915 @default.
- W4291567125 cites W2885244888 @default.
- W4291567125 cites W2888889240 @default.
- W4291567125 cites W2900661164 @default.
- W4291567125 cites W2901987115 @default.
- W4291567125 cites W2903258775 @default.
- W4291567125 cites W2905734232 @default.
- W4291567125 cites W2910995260 @default.
- W4291567125 cites W2940331834 @default.
- W4291567125 cites W2943575207 @default.
- W4291567125 cites W2945944081 @default.
- W4291567125 cites W2949627955 @default.
- W4291567125 cites W2950611731 @default.
- W4291567125 cites W2951462864 @default.
- W4291567125 cites W2964914351 @default.
- W4291567125 cites W2972512495 @default.
- W4291567125 cites W2979975554 @default.
- W4291567125 cites W2991460196 @default.
- W4291567125 cites W2994910631 @default.
- W4291567125 cites W2998877393 @default.
- W4291567125 cites W3001508512 @default.
- W4291567125 cites W3009040199 @default.
- W4291567125 cites W3013413336 @default.
- W4291567125 cites W3013917632 @default.
- W4291567125 cites W3038951056 @default.
- W4291567125 cites W3046225271 @default.
- W4291567125 cites W3047608782 @default.
- W4291567125 cites W3084284706 @default.
- W4291567125 cites W3086553733 @default.
- W4291567125 cites W3090373012 @default.
- W4291567125 cites W3098324797 @default.
- W4291567125 cites W3110939857 @default.
- W4291567125 cites W3112743907 @default.
- W4291567125 cites W3117257671 @default.
- W4291567125 cites W3119789537 @default.
- W4291567125 cites W3126991744 @default.
- W4291567125 cites W3127373363 @default.
- W4291567125 cites W3128724272 @default.
- W4291567125 cites W3134331446 @default.