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- W4292018449 abstract "We report a simple, postsynthetic strategy for synthesis of oligonucleotides containing 2,6-diaminopurine nucleotides and 2-aminoadenine conjugates using 2-fluoro-6-amino-adenosine. The strategy allows introduction of 2,6-diaminopurine and other 2-amino group-containing ligands. The strongly electronegative 2-fluoro deactivates 6-NH2 obviating the need for any protecting group on adenine, and simple aromatic nucleophilic substitution of fluorine makes reaction with aqueous NH3 or R-NH2 feasible at the 2-position." @default.
- W4292018449 created "2022-08-17" @default.
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- W4292018449 date "2022-08-16" @default.
- W4292018449 modified "2023-09-29" @default.
- W4292018449 title "A Chemical Approach to Introduce 2,6-Diaminopurine and 2-Aminoadenine Conjugates into Oligonucleotides without Need for Protecting Groups" @default.
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- W4292018449 doi "https://doi.org/10.1021/acs.orglett.2c01848" @default.
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