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• W4292092812 abstract "Abstract Because C 2 H 4 plays an essential role in the chemical industry, economical and energy‐efficient separation of ethylene (C 2 H 4 ) from ethane (C 2 H 6 ) is extremely important. With the exception of energy‐intensive cryogenic distillation, there are few one‐step methods to obtain polymer‐grade (≥99.95 % pure) C 2 H 4 from C 2 H 4 /C 2 H 6 mixtures. Here we report a highly stable metal‐organic‐framework (MOF) FJI‐H11‐Me(des) (FJI‐H=Hong's group in Fujian Institute of Research on the Structure of Matter) which features one‐dimensional hexagonal nonpolar pore surfaces constructed by aromatic rings and alkyl groups. This FJI‐H11‐Me(des) adsorbs C 2 H 6 rather than C 2 H 4 between 273 and 303 K. Practical breakthrough experiments with C 2 H 4 containing 1 % C 2 H 6 have shown that FJI‐H11‐Me(des) can realize the acquisition in one‐step of polymer‐grade, 99.95 % pure C 2 H 4 under various conditions including different gas flow rates, temperatures and relative humidity." @default.
• W4292092812 created "2022-08-17" @default.
• W4292092812 creator A5007713020 @default.
• W4292092812 creator A5009734574 @default.
• W4292092812 creator A5026733759 @default.
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• W4292092812 creator A5049053873 @default.
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• W4292092812 creator A5055908057 @default.
• W4292092812 creator A5064548129 @default.
• W4292092812 creator A5070523720 @default.
• W4292092812 creator A5084619384 @default.
• W4292092812 date "2022-08-31" @default.
• W4292092812 modified "2023-10-17" @default.
• W4292092812 title "A Metal‐Organic Framework with Nonpolar Pore Surfaces for the One‐Step Acquisition of C₂H₄ from a C₂H₄ and C₂H₆ Mixture" @default.
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• W4292092812 doi "https://doi.org/10.1002/anie.202210343" @default.
• W4292092812 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35975940" @default.

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