Matches in SemOpenAlex for { <https://semopenalex.org/work/W4292117316> ?p ?o ?g. }
- W4292117316 endingPage "120920" @default.
- W4292117316 startingPage "120920" @default.
- W4292117316 abstract "A high-quality mixed matrix membrane (MMM) with high flux and separation factor is fostered to enhance ethanol pervaporation. In this study, a fluorinated and defect-free ZIF-8/PDMS membrane was prepared by the covalent bonding among fluoromonomer, ZIF-8 particles and PDMS using a one-pot method. ZIF-8 is first modified with 3-amino-1,2,4-triazole (Atz) to graft –NH2 groups, and then modified with glycidyl methacrylate (GMA). This was achieved by the amine-epoxide addition reaction (named GZIF-8) to facilitate covalent bonding with methacrylate-functionalized PDMS, where the interfacial compatibility ZIF-8 and PDMS is improved. Moreover, 1H,1H,2H,2H-perfluorooctyl methacrylate (13F) as F-monomer is introduced into the membrane formation process by the polymerization of methacrylate groups among 13F, ZIF-8 and PDMS, where a fluorinated structure with high hydrophobicity and low surface energy is formed. The pervaporation performance for a 5 wt% ethanol solution at 60 °C shows that the resulting MMM has a high separation factor of 9.5 and total flux of 1681 g m−2 h−1 under the optimized parameters of 3 wt% GZIF-8 loading and 12 wt% 13F amounts." @default.
- W4292117316 created "2022-08-17" @default.
- W4292117316 creator A5001371988 @default.
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- W4292117316 creator A5021489833 @default.
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- W4292117316 creator A5079483408 @default.
- W4292117316 creator A5082339583 @default.
- W4292117316 creator A5090605740 @default.
- W4292117316 date "2022-11-01" @default.
- W4292117316 modified "2023-10-18" @default.
- W4292117316 title "A fluorinated, defect-free ZIF-8/PDMS mixed matrix membrane for enhancing ethanol pervaporation" @default.
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