Matches in SemOpenAlex for { <https://semopenalex.org/work/W4292183612> ?p ?o ?g. }
- W4292183612 endingPage "1146" @default.
- W4292183612 startingPage "1129" @default.
- W4292183612 abstract "The ruthenium complexes, [Ph2PN(R)PPh2]2RuCl2, where R = C6H11 (a); C3H7 (b); C5H11 (c), have been synthesized and characterized. These complexes were studied for n-octane and styrene oxidation with different hybridizations of CH bonds. Ru-oxo species were identified as active species in both reactions but showed very different catalytic behavior in the chosen catalytic models. These complexes were good candidates to catalyze C1 partial oxidation and result in high selectivity to octanal and 1-octanol, which have high industrial demand as precursors to α-octene (a good elasticizer for the polymer industry). Slight modification of the ligand backbone influenced both the rate of Ru-oxo formation and their nature. This resulted in different selectivity and conversion in both the studied oxidative reactions. These studies provide insights regarding the role and the mode of action of metal-oxo species during oxidation reactions, which is of interest to researchers in the field of homogenous catalysis." @default.
- W4292183612 created "2022-08-18" @default.
- W4292183612 creator A5015409293 @default.
- W4292183612 creator A5023979760 @default.
- W4292183612 creator A5051985429 @default.
- W4292183612 creator A5065078779 @default.
- W4292183612 date "2022-05-19" @default.
- W4292183612 modified "2023-09-26" @default.
- W4292183612 title "New Ru PNP complexes as in situ Ru-oxo precursors in styrene and octane oxidation" @default.
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