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• W4292183672 endingPage "11592" @default.
• W4292183672 startingPage "11583" @default.
• W4292183672 abstract "We disclose the first accomplishment of the azo-Povarov reaction involving Sc(OTf)3-catalyzed [4 + 2] annulations of N-carbonyl aryldiazenes with cyclopentadiene in chloroform, in which N-carbonyl aryldiazenes act as 4π-electron donors. Hence, this protocol offers a rapid access to an array of cinnoline derivatives in moderate to good yields for substrates over a wide scope. The synthetic potential of the protocol was achieved by the gram-scale reaction and further derivatization of the obtained polycyclic product." @default.
• W4292183672 created "2022-08-18" @default.
• W4292183672 creator A5002886577 @default.
• W4292183672 creator A5060696796 @default.
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• W4292183672 date "2022-08-16" @default.
• W4292183672 modified "2023-09-26" @default.
• W4292183672 title "Sc(OTf)₃-Mediated [4 + 2] Annulations of <i>N</i>-Carbonyl Aryldiazenes with Cyclopentadiene to Construct Cinnoline Derivatives: Azo-Povarov Reaction" @default.
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• W4292183672 doi "https://doi.org/10.1021/acs.joc.2c01224" @default.
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