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- W4292227855 abstract "Until now, it has been assumed that the primary decomposition pathway for the liquid plasticizer bis(2,2-dinitropropyl)acetal and bis(2,2-dinitropropyl)formal (BDNPA/F) was nitrous acid elimination (NAE). An ultrahigh-performance liquid chromatography (UHPLC) coupled to quadrupole time-of-flight mass spectrometry (QTOF) methodology was developed to discover and identify the degradation products of BDNPA/F. No evidence of NAE was found. However, two other degradation pathways were found: (1) hydrolysis of the acetal/formal functional group and (2) radical-based homolysis of the C–N bond, followed by hydrogen atom abstraction. Hydrolysis of BDNPA/F proceeds by the formation of 2,2-dinitropropanol (DNPOH) and 2,2-dinitropropyl hemiacetal/hemiformal, which further decompose into DNPOH and ethanal/methanal, respectively. Hydrolysis is the dominant decomposition pathway in all samples; however, at higher temperatures, C–N homolysis becomes more significant. Also, the solid PBX 9501 has different ratios of decomposition products than the liquid BDNPA/F due to the slower rate of diffusion through solids than liquids." @default.
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- W4292227855 date "2022-08-18" @default.
- W4292227855 modified "2023-09-25" @default.
- W4292227855 title "Investigation into the Decomposition Pathways of an Acetal-Based Plasticizer" @default.
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- W4292227855 doi "https://doi.org/10.1021/acsomega.2c03494" @default.
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