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• W4292292046 endingPage "36526" @default.
• W4292292046 startingPage "36515" @default.
• W4292292046 abstract "Metal–organic frameworks (MOFs) and metal halide perovskites are currently under much investigation due to their unique properties and applications. Herein, an innovative strategy has been developed combining an iron-porphyrin MOF, PCN-222(Fe), and an in situ-grown CsCu2I3 nontoxic lead-free halide perovskite based on an earth-abundant metal that becomes incorporated within the MOF channels [CsCu2I3@PCN-222(Fe)]. Encapsulation was designed to decrease and control the particle size and increase the stability of CsCu2I3. The hybrid materials were characterized by various techniques including FE-SEM, elemental mapping and line scanning EDX, TEM, PXRD, UV–Vis DRS, BET surface area, XPS, and photoemission measurements. Hybrid CsCu2I3@PCN-222(Fe) materials were examined as heterogeneous multifunctional (photo)catalysts for copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC) and one-pot selective photo-oxidation/Knoevenagel condensation cascade reaction. Interestingly, CsCu2I3@PCN-222(Fe) outperforms not only its individual components CsCu2I3 and PCN-222(Fe) but also other reported (photo)catalysts for these transformations. This is attributed to cooperation and synergistic effects of the PCN-222(Fe) host and CsCu2I3 nanocrystals. To understand the catalytic and photocatalytic mechanisms, control and inhibition experiments, electron paramagnetic resonance (EPR) measurements, and time-resolved phosphorescence were performed, revealing the main role of active species of Cu(I) in the click reaction and the superoxide ion (O2•–) and singlet oxygen (1O2) in the photocatalytic reaction." @default.
• W4292292046 created "2022-08-19" @default.
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• W4292292046 date "2022-08-08" @default.
• W4292292046 modified "2023-09-30" @default.
• W4292292046 title "CsCu₂I₃ Nanoparticles Incorporated within a Mesoporous Metal–Organic Porphyrin Framework as a Catalyst for One-Pot Click Cycloaddition and Oxidation/Knoevenagel Tandem Reaction" @default.
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• W4292292046 doi "https://doi.org/10.1021/acsami.2c04364" @default.
• W4292292046 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35939817" @default.
• W4292292046 hasPublicationYear "2022" @default.
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