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- W4292405917 abstract "Sodium-ion batteries have significant advantages in the field of large-scale energy storage due to their low cost, abundant sodium resources, and appropriate redox potential. Na3V2(PO4)3 with a unique NASICON structure demonstrates a high voltage platform and high capacity. However, the low electronic conductivity of Na3V2(PO4)3 causes it to have poor cycling stability and rate capability. High-conductivity carbon materials can enhance the Na3V2(PO4)3’s poor electronic conductivity. In this study, Na3V2(PO4)3 nanoparticles were evenly distributed in the carbon skeleton’s porous structure by a simple impregnation approach using daily necessities cotton soft tissue as a new carbon source. The prepared Na3V2(PO4)3/C cathode material with a three-dimensional (3D) interconnected porous structure shows better electrochemical properties than pure Na3V2(PO4)3. The first discharge specific capacity of Na3V2(PO4)3/C material at 0.1 C is 106.4 mAh g−1 in the voltage range of 2–4.0 V. The material’s capacity can still remain stable after 2000 cycles at 2 C and 5 C rates. The presence of 3D interconnected porous carbon significantly enhances the electronic conductivity of Na3V2(PO4)3 material, shortens the ion diffusion path, speeds up the electron transfer, and inhibits electrode/electrolyte interface side reactions. Several common carbon sources in everyday life are promising auxiliary materials for enhancing the electrochemical properties of electrode materials used in secondary batteries." @default.
- W4292405917 created "2022-08-20" @default.
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- W4292405917 date "2022-10-01" @default.
- W4292405917 modified "2023-10-13" @default.
- W4292405917 title "Na3V2(PO4)3/C cathode material with three-dimensional interconnected porous structure constructed using cotton soft tissue as carbon source" @default.
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- W4292405917 doi "https://doi.org/10.1016/j.inoche.2022.109881" @default.
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