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- W4292543313 abstract "Abstract Herein, we report our results on the synthetic studies of the originally proposed structure of protoaculeine B, isolated from a marine sponge. Starting from tryptophan, two candidates of the suitably protected heterotricyclic subunits were stereoselectively synthesized over 8 and 16 steps, respectively. Furthermore, two diastereomeric heterotricyclic amino acids, finally synthesized, were found to be neuroactive: the (9 S *,11 S *)‐isomer with natural‐type configuration was hyperactive, whereas diastereomeric (9 S *,11 R *)‐isomer was hypoactive upon mice intracerebroventricular injection." @default.
- W4292543313 created "2022-08-22" @default.
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- W4292543313 date "2022-09-27" @default.
- W4292543313 modified "2023-09-26" @default.
- W4292543313 title "Synthetic Studies on the Initially Proposed Structure of Protoaculeine B: Discovery of Neuronally Active Heterotricyclic Amino Acids" @default.
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- W4292543313 doi "https://doi.org/10.1002/ejoc.202200669" @default.
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