Matches in SemOpenAlex for { <https://semopenalex.org/work/W4292553399> ?p ?o ?g. }
Showing items 1 to 68 of
68
with 100 items per page.
- W4292553399 abstract "The selective hydrogenation of CO2 to methanol by renewable hydrogen source represents an attractive route for CO2 recycling and carbon neutral. Stable catalysts with high activity and methanol selectivity are being hotly pursued, and current debates on the active site and reaction pathway need to be clarified. Here, we report the design of faujasite-encaged mononuclear Cu centers, namely Cu@FAU, for this challenging reaction. Stable methanol space-time-yield (STY) of 12.8 mmol/gcat/h and methanol selectivity of 89.5 % are simultaneously achieved at a relatively low reaction temperature of 513 K, making Cu@FAU a potential methanol synthesis catalyst from CO2 hydrogenation. With zeolite-encaged mononuclear Cu centers as the destined active sites, the unique reaction pathway of stepwise CO2 hydrogenation over Cu@FAU is illustrated. This work provides an elegant example of catalytic reaction with explicit structure-activity relationship and highlights the power of zeolite catalysis in complex chemical transformations." @default.
- W4292553399 created "2022-08-22" @default.
- W4292553399 creator A5010289866 @default.
- W4292553399 creator A5010733298 @default.
- W4292553399 creator A5013494266 @default.
- W4292553399 creator A5026372235 @default.
- W4292553399 creator A5060836346 @default.
- W4292553399 creator A5087343432 @default.
- W4292553399 creator A5091005428 @default.
- W4292553399 date "2022-08-22" @default.
- W4292553399 modified "2023-10-18" @default.
- W4292553399 title "CO2 hydrogenation to methanol over zeolite-encaged mononuclear copper centers" @default.
- W4292553399 doi "https://doi.org/10.26434/chemrxiv-2022-w69zl" @default.
- W4292553399 hasPublicationYear "2022" @default.
- W4292553399 type Work @default.
- W4292553399 citedByCount "0" @default.
- W4292553399 crossrefType "posted-content" @default.
- W4292553399 hasAuthorship W4292553399A5010289866 @default.
- W4292553399 hasAuthorship W4292553399A5010733298 @default.
- W4292553399 hasAuthorship W4292553399A5013494266 @default.
- W4292553399 hasAuthorship W4292553399A5026372235 @default.
- W4292553399 hasAuthorship W4292553399A5060836346 @default.
- W4292553399 hasAuthorship W4292553399A5087343432 @default.
- W4292553399 hasAuthorship W4292553399A5091005428 @default.
- W4292553399 hasBestOaLocation W42925533991 @default.
- W4292553399 hasConcept C118792377 @default.
- W4292553399 hasConcept C134121241 @default.
- W4292553399 hasConcept C161790260 @default.
- W4292553399 hasConcept C178790620 @default.
- W4292553399 hasConcept C179104552 @default.
- W4292553399 hasConcept C185592680 @default.
- W4292553399 hasConcept C191897082 @default.
- W4292553399 hasConcept C192562407 @default.
- W4292553399 hasConcept C2776020506 @default.
- W4292553399 hasConcept C2778077586 @default.
- W4292553399 hasConcept C2779607525 @default.
- W4292553399 hasConcept C512968161 @default.
- W4292553399 hasConcept C544778455 @default.
- W4292553399 hasConceptScore W4292553399C118792377 @default.
- W4292553399 hasConceptScore W4292553399C134121241 @default.
- W4292553399 hasConceptScore W4292553399C161790260 @default.
- W4292553399 hasConceptScore W4292553399C178790620 @default.
- W4292553399 hasConceptScore W4292553399C179104552 @default.
- W4292553399 hasConceptScore W4292553399C185592680 @default.
- W4292553399 hasConceptScore W4292553399C191897082 @default.
- W4292553399 hasConceptScore W4292553399C192562407 @default.
- W4292553399 hasConceptScore W4292553399C2776020506 @default.
- W4292553399 hasConceptScore W4292553399C2778077586 @default.
- W4292553399 hasConceptScore W4292553399C2779607525 @default.
- W4292553399 hasConceptScore W4292553399C512968161 @default.
- W4292553399 hasConceptScore W4292553399C544778455 @default.
- W4292553399 hasLocation W42925533991 @default.
- W4292553399 hasLocation W42925533992 @default.
- W4292553399 hasOpenAccess W4292553399 @default.
- W4292553399 hasPrimaryLocation W42925533991 @default.
- W4292553399 hasRelatedWork W1968040991 @default.
- W4292553399 hasRelatedWork W1980930998 @default.
- W4292553399 hasRelatedWork W1996283073 @default.
- W4292553399 hasRelatedWork W2013417974 @default.
- W4292553399 hasRelatedWork W2074624826 @default.
- W4292553399 hasRelatedWork W2080070073 @default.
- W4292553399 hasRelatedWork W2267675618 @default.
- W4292553399 hasRelatedWork W2365253989 @default.
- W4292553399 hasRelatedWork W3011590888 @default.
- W4292553399 hasRelatedWork W3136593198 @default.
- W4292553399 isParatext "false" @default.
- W4292553399 isRetracted "false" @default.
- W4292553399 workType "article" @default.