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- W4292559753 endingPage "107910" @default.
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- W4292559753 abstract "• Co, N -doped-porous carbon rods was obtained by calcination of bimetallic ZIFs. • CoN-PCR-0.6 modified electrode was employed to monitor nitrite. • Efficient detection originates from porous structure, N -doping, and embedded Co. Measurement of nitrite is needed for the control of nitrite pollution and to decrease the health risks and protect environment. It is attractive to design novel electrocatalysts for the efficient electrochemical quantification of nitrite. Herein, a sequence of Co, N -doped-porous carbon rods (CoN-PCRs) were designed and prepared through the calcination of rod-shaped mixed-metal zeolitic imidazolate framework precursors (ZIF-L) with different Co/Zn ratios. It was observed that the highest surface area and best response were obtained with the CoN-PCRs-0.6. Furthermore, its morphology and structure were characterized by several techniques. Additionally, the electrochemical sensing performances of CoN-PCRs-0.6 to nitrite were studied. Benefiting from the structural merits, the constructed sensor showed a low detection limit of 0.14 μM and achieved two wide dynamic ranges 0.2–4000 μM and 4000–100000 μM. The sensor also possessed good specificity, reproducibility, and stability toward nitrite quantification. Ultimately, the rapid and accurate measurement of nitrite in tap water was successfully realized." @default.
- W4292559753 created "2022-08-22" @default.
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- W4292559753 date "2022-11-01" @default.
- W4292559753 modified "2023-10-09" @default.
- W4292559753 title "A nitrite sensor based on bimetallic zeolitic imidazole framework derived Co/porous carbon nanorods" @default.
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- W4292559753 doi "https://doi.org/10.1016/j.microc.2022.107910" @default.
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