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- W4292731104 abstract "Chiral perovskites have recently generated significant interest, yet little is known about how their chiro-optical properties arise. In this study, chiral methylammonium lead halide perovskite nanoplatelets (NPLs) with varied halide and ligand compositions are prepared by using direct synthetic methods. Circular dichroism (CD) and 1H NMR studies find a nonlinear relationship between the chiroptical properties and the ratio of chiral phenylethylammonium (PEA) to achiral octylamine (OA) ligands on the NPL surface. We use density functional theory (DFT) computations and a chiral imprinted particle-in-a-box model to rationalize the experimentally observed CD spectra, and we find that the saturation of the induced chirality depends on the size of the perovskite exciton relative to the size of the ligand moleclues. Temperature-dependent CD and 1H NMR studies, combined with DFT analysis, show that both the CD intensity and sign depend strongly on the structure and orientation of the ligands. This work reveals the complex nature of chiral imprinting in perovskite nanostructures and establishes a simple physical model for ligand-induced chiral imprinting to guide the further development of chiral materials." @default.
- W4292731104 created "2022-08-23" @default.
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- W4292731104 date "2022-08-23" @default.
- W4292731104 modified "2023-10-15" @default.
- W4292731104 title "Ligand Coverage and Exciton Delocalization Control Chiral Imprinting in Perovskite Nanoplatelets" @default.
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- W4292731104 doi "https://doi.org/10.1021/acs.jpcc.2c04192" @default.
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