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- W4292749540 abstract "A convergent strategy for the synthesis of leustroducsins and phoslactomycins has been designed, relying on the synthesis and the coupling of three main fragments. The central fragment was synthesized via a regio-and stereoselective nitroso Diels-Alder with an enol phosphate, followed by reductive cleavage of the phosphate to the ketone 11b . Coupling studies of this fragment with the lactone fragment was accomplished in a stereoselective fashion through a vinyl lithium intermediate. An advanced synthetic intermediate was then obtained after functional group transformation." @default.
- W4292749540 created "2022-08-23" @default.
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- W4292749540 date "2022-08-23" @default.
- W4292749540 modified "2023-09-29" @default.
- W4292749540 title "Synthesis of an Advanced Intermediate for Leustroducsins and Phoslactomycins Synthesis by Heterocycloaddition" @default.
- W4292749540 doi "https://doi.org/10.3762/bxiv.2022.69.v1" @default.
- W4292749540 hasPublicationYear "2022" @default.
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