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• W4293090007 abstract "In situ X-ray absorption spectroscopy (XAS) is a powerful technique for the investigation of heterogeneous catalysts and electrocatalysts. The obtained XAS spectra are usually interpreted from the point of view of the investigated chemical processes, thereby sometimes omitting the fact that intense X-ray irradiation may induce additional transformations in metal speciation and, thus, in the corresponding XAS spectra. In this work, we report on X-ray induced photochemical reduction of vanadium in supported vanadia (VOx) catalysts under reaction conditions, detected at a synchrotron beamline. While this process was not observed in an inert atmosphere and in the presence of water vapor, it occurred at room temperature in the presence of a reducing agent (ethanol or hydrogen) alone or mixed with oxygen. Temperature programmed experiments have shown that X-ray induced reduction of VOx species appeared very clear at 30-100 °C but was not detected at higher temperatures, where the thermocatalytic ethanol oxidative hydrogenation (ODH) takes place. Similar to other studies on X-ray induced effects, we suggest approaches, which can help to mitigate vanadium photoreduction, including defocusing of the X-ray beam and attenuation of the X-ray beam intensity by filters. To recognize beam damage under in situ/operando conditions, we suggest performing X-ray beam switching (on and off) tests at different beam intensities under in situ conditions." @default.
• W4293090007 created "2022-08-26" @default.
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• W4293090007 date "2022-01-01" @default.
• W4293090007 modified "2023-10-01" @default.
• W4293090007 title "Beware of beam damage under reaction conditions: X-ray induced photochemical reduction of supported VO_<i>x</i> catalysts during <i>in situ</i> XAS experiments" @default.
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• W4293090007 cites W1977949438 @default.
• W4293090007 cites W1980461125 @default.
• W4293090007 cites W1985727049 @default.
• W4293090007 cites W1987194367 @default.
• W4293090007 cites W1991824447 @default.
• W4293090007 cites W1992507915 @default.
• W4293090007 cites W199969809 @default.
• W4293090007 cites W2000390034 @default.
• W4293090007 cites W2000990108 @default.
• W4293090007 cites W2001400828 @default.
• W4293090007 cites W2001492509 @default.
• W4293090007 cites W2003532522 @default.
• W4293090007 cites W2009739472 @default.
• W4293090007 cites W2028983717 @default.
• W4293090007 cites W2031393568 @default.
• W4293090007 cites W2037315387 @default.
• W4293090007 cites W2047552806 @default.
• W4293090007 cites W2048123141 @default.
• W4293090007 cites W2057044003 @default.
• W4293090007 cites W2060055202 @default.
• W4293090007 cites W2061754927 @default.
• W4293090007 cites W2068043331 @default.
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• W4293090007 cites W2073747944 @default.
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• W4293090007 cites W2083678930 @default.
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• W4293090007 cites W2133390946 @default.
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• W4293090007 cites W2289403203 @default.
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• W4293090007 doi "https://doi.org/10.1039/d2cp02721f" @default.
• W4293090007 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36069029" @default.
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