Matches in SemOpenAlex for { <https://semopenalex.org/work/W4293219087> ?p ?o ?g. }
- W4293219087 abstract "Abstract Tetra‐ ortho ‐substituted, heteroaryl and cyclic azobenzenes have emerged as three key strategies on morphology design of photoswitch to diversify controllability. Cyclic azobenzene is of particular utilization in photo‐energy conversion due to rigid and ring‐strain structure. Despite the well‐recognized diazocine, the photo‐switching properties of seven‐membered cyclic azobenzenes (diazepines) have yet been exploited. Herein, we report a family of dibenzo[ b,f ][1,4,5]chalcogenadiazepines (DBChDs) and their T‐type photo‐switching nature with tunable relaxation rate. Based on experiments together with DFT calculations, we found that an unsymmetric 2‐bithiophenyl‐dibenzo[ b,f ][1,4,5]thiadiazepine exhibited an efficient response to 445 nm laser stimulation (quantum efficiency, Φ Z→E =0.71) with millisecond relaxation half‐life ( t 1/2 =40 ms). Photo‐energy transduction efficiency was also exceptionally high with 29.1 % converted into ring‐strain energy mainly loaded on azo π‐bond." @default.
- W4293219087 created "2022-08-27" @default.
- W4293219087 creator A5002419843 @default.
- W4293219087 creator A5027249460 @default.
- W4293219087 creator A5040530717 @default.
- W4293219087 creator A5042390620 @default.
- W4293219087 creator A5047257643 @default.
- W4293219087 creator A5048671077 @default.
- W4293219087 creator A5050027776 @default.
- W4293219087 creator A5052356951 @default.
- W4293219087 creator A5063980828 @default.
- W4293219087 creator A5070008862 @default.
- W4293219087 creator A5072536000 @default.
- W4293219087 creator A5076559176 @default.
- W4293219087 creator A5089492877 @default.
- W4293219087 date "2022-09-07" @default.
- W4293219087 modified "2023-10-17" @default.
- W4293219087 title "Dibenzo[<i>b</i>,<i>f</i>][1,4,5]chalcogenadiazepine Photoswitches: Conversion of Excitation Energy into Ring Strain" @default.
- W4293219087 cites W1971933638 @default.
- W4293219087 cites W1989854295 @default.
- W4293219087 cites W2006277163 @default.
- W4293219087 cites W2009483611 @default.
- W4293219087 cites W2034097144 @default.
- W4293219087 cites W2085499026 @default.
- W4293219087 cites W2095565245 @default.
- W4293219087 cites W2111966734 @default.
- W4293219087 cites W2132525235 @default.
- W4293219087 cites W2145433313 @default.
- W4293219087 cites W2148734015 @default.
- W4293219087 cites W2158788902 @default.
- W4293219087 cites W2166498854 @default.
- W4293219087 cites W2172413067 @default.
- W4293219087 cites W2312858765 @default.
- W4293219087 cites W2331160118 @default.
- W4293219087 cites W2463040786 @default.
- W4293219087 cites W2525478871 @default.
- W4293219087 cites W2530773901 @default.
- W4293219087 cites W2769872877 @default.
- W4293219087 cites W2780825361 @default.
- W4293219087 cites W2782444079 @default.
- W4293219087 cites W2814854939 @default.
- W4293219087 cites W2890553452 @default.
- W4293219087 cites W2914372734 @default.
- W4293219087 cites W2944780248 @default.
- W4293219087 cites W2949582813 @default.
- W4293219087 cites W2965029365 @default.
- W4293219087 cites W2970232210 @default.
- W4293219087 cites W3010335987 @default.
- W4293219087 cites W3012673328 @default.
- W4293219087 cites W3012862723 @default.
- W4293219087 cites W3019080808 @default.
- W4293219087 cites W3027358968 @default.
- W4293219087 cites W3034666461 @default.
- W4293219087 cites W3038366758 @default.
- W4293219087 cites W3039270016 @default.
- W4293219087 cites W3049528242 @default.
- W4293219087 cites W3092768003 @default.
- W4293219087 cites W3109471828 @default.
- W4293219087 cites W3110492260 @default.
- W4293219087 cites W3129727244 @default.
- W4293219087 cites W3135448319 @default.
- W4293219087 cites W3135542571 @default.
- W4293219087 cites W3157076444 @default.
- W4293219087 cites W3165596381 @default.
- W4293219087 cites W3173420259 @default.
- W4293219087 cites W3184121714 @default.
- W4293219087 cites W3199752245 @default.
- W4293219087 cites W3201002617 @default.
- W4293219087 cites W3203866909 @default.
- W4293219087 cites W3212954605 @default.
- W4293219087 cites W4206075448 @default.
- W4293219087 cites W4212890514 @default.
- W4293219087 cites W4214666672 @default.
- W4293219087 cites W4214721599 @default.
- W4293219087 cites W4221079931 @default.
- W4293219087 cites W4226344220 @default.
- W4293219087 cites W4248893842 @default.
- W4293219087 cites W4249878000 @default.
- W4293219087 cites W4254121907 @default.
- W4293219087 cites W4386008417 @default.
- W4293219087 doi "https://doi.org/10.1002/ange.202209441" @default.
- W4293219087 hasPublicationYear "2022" @default.
- W4293219087 type Work @default.
- W4293219087 citedByCount "0" @default.
- W4293219087 crossrefType "journal-article" @default.
- W4293219087 hasAuthorship W4293219087A5002419843 @default.
- W4293219087 hasAuthorship W4293219087A5027249460 @default.
- W4293219087 hasAuthorship W4293219087A5040530717 @default.
- W4293219087 hasAuthorship W4293219087A5042390620 @default.
- W4293219087 hasAuthorship W4293219087A5047257643 @default.
- W4293219087 hasAuthorship W4293219087A5048671077 @default.
- W4293219087 hasAuthorship W4293219087A5050027776 @default.
- W4293219087 hasAuthorship W4293219087A5052356951 @default.
- W4293219087 hasAuthorship W4293219087A5063980828 @default.
- W4293219087 hasAuthorship W4293219087A5070008862 @default.
- W4293219087 hasAuthorship W4293219087A5072536000 @default.
- W4293219087 hasAuthorship W4293219087A5076559176 @default.
- W4293219087 hasAuthorship W4293219087A5089492877 @default.
- W4293219087 hasConcept C107111320 @default.
- W4293219087 hasConcept C120665830 @default.