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- W4293237321 abstract "Among the famous Daphniphyllum alkaloids family, the calyciphylline A-type subfamily has triggered particular interest from the organic synthesis community in recent years. Here, we report divergent total syntheses of three calyciphylline A-type alkaloids, namely, (-)-10-deoxydaphnipaxianine A, (+)-daphlongamine E, and (+)-calyciphylline R. Our work highlights an efficient, divergent strategy via late-stage divinyl carbinol rearrangements, including an unprecedented oxidative Nazarov electrocyclization using an unfunctionalized tertiary divinyl carbinol and an unusual allylic alcohol rearrangement. A highly efficient donor-acceptor platinum catalyst was used for a critical nitrile hydration step. Moreover, the power of selective amide reductions has also been showcased by novel and classic tactics." @default.
- W4293237321 created "2022-08-27" @default.
- W4293237321 creator A5010941377 @default.
- W4293237321 creator A5011497989 @default.
- W4293237321 creator A5014648236 @default.
- W4293237321 creator A5042934875 @default.
- W4293237321 creator A5044113465 @default.
- W4293237321 creator A5047129925 @default.
- W4293237321 creator A5058689861 @default.
- W4293237321 creator A5072989519 @default.
- W4293237321 creator A5086664284 @default.
- W4293237321 creator A5088895071 @default.
- W4293237321 creator A5090668182 @default.
- W4293237321 date "2022-08-25" @default.
- W4293237321 modified "2023-10-09" @default.
- W4293237321 title "Total Syntheses of Calyciphylline A-Type Alkaloids (−)-10-Deoxydaphnipaxianine A, (+)-Daphlongamine E and (+)-Calyciphylline R via Late-Stage Divinyl Carbinol Rearrangements" @default.
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