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- W4293242253 abstract "Herein, the asymmetric synthesis of umuravumbolide (1) is described. The new approach features highly stereoselective transformations (dr ≥ 95:5) to install both stereocenters and the Z olefin, which involve a new radical alkylation, an Ando olefination, and a Krische allylation on a Z allylic alcohol, not reported before. The application of such successful reactions, together with the limited use of protecting groups and concession steps, makes it possible to complete the synthesis in 10 steps, resulting in a 39% overall yield from chiral N-acyl oxazolidinone 2." @default.
- W4293242253 created "2022-08-27" @default.
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- W4293242253 date "2022-08-25" @default.
- W4293242253 modified "2023-10-17" @default.
- W4293242253 title "Optimized Asymmetric Synthesis of Umuravumbolide" @default.
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- W4293242253 doi "https://doi.org/10.1021/acsomega.2c02304" @default.
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