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- W4293339968 abstract "The concept of single-layer cluster adsorption and a new scientific understanding of single-layer adsorption by porous and non-porous sorbents are proposed. The model expands the understanding of the physical adsorption, where sorbate-sorbate bonds make a significant contribution to the adsorption energy. The fundamental difference between proposed adsorption picture and the traditional one is the representation of one sorption center as the center of fixation of several molecules for porous systems. An analytical expression for adsorption isotherm have been obtained from equilibrium coefficients expressions of the adsorption processes, expressed via surface coverage fraction by adsorbed molecules. The developed model supplements the adsorption theory. A geometric method is described for the parameters determining of the simplified model. The model is applied to the interpretation of CO 2 adsorption isotherms by metal-organic frameworks MOF-177, IRMOF-1, IRMOF-6 and IRMOF-11." @default.
- W4293339968 created "2022-08-27" @default.
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- W4293339968 date "2022-12-01" @default.
- W4293339968 modified "2023-09-27" @default.
- W4293339968 title "Single-layer cluster adsorption model and its application for the estimation of the CO2 structure on metal-organic frameworks" @default.
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- W4293339968 doi "https://doi.org/10.1016/j.mtcomm.2022.104327" @default.
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