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• W4293569686 abstract "The structural evolution and magnetic properties of Nd5Ge3-xSix (0 ≤ x ​≤ ​3) compounds have been investigated. With increasing Si substitution amount, the crystallographic structure of Nd5Ge3-xSix compounds gradually changes from the hexagonal Mn5Si3-type one for x ​≤ ​1 to the tetragonal Cr5B3-type one for 2.5 ≤ x ​≤ ​3. For the compounds with the Mn5Si3-type hexagonal structure, the phase transition temperatures are 42 ​K and 45 ​K in Nd5Ge2.5Si0.5 and Nd5Ge2Si compounds, and the values of the corresponding maximum magnetic entropy change (− ​ΔSMmax) are 6.0 Jkg-1 K−1 and 6.0 Jkg-1 K−1 under the field change of 7 ​T. For the compounds with the Cr5B3-type tetragonal structure, the Curie temperature (Tc) of Nd5Si2.5Ge0.5 is 123 ​K compared with 112 ​K of Nd5Si3. For the field change of 7 ​T, the maximum magnetic entropy change is 3.9 Jkg-1 K−1 of Nd5Ge0.5Si2.5 and 4.3 Jkg-1 K−1 of Nd5Si3 compounds." @default.
• W4293569686 created "2022-08-30" @default.
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• W4293569686 date "2022-11-01" @default.
• W4293569686 modified "2023-10-16" @default.
• W4293569686 title "Structural evolution and magnetic phase transitions of Nd5Ge3-Si (0 ≤ x ≤ 3) compounds" @default.
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• W4293569686 doi "https://doi.org/10.1016/j.jssc.2022.123533" @default.
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