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- W4293577557 abstract "• Bromothymol blue's spectral properties were recorded in the presence of heavy water and of some selected electrolytes. • The removal of dissolved gases from the dye solution modifies its UV–vis absorption spectrum. • Re-admitted gases induce specific effects on the spectral features of the dye. The color of the pH indicator Bromothymol blue (BTB) changes from yellow to blue with increasing pH. The effect of some electrolytes (LiCl, NaCl, KCl, CsCl, KSCN and KClO 3 ) and of D 2 O on the spectral properties of dilute solutions of BTB is explored. The results are interpreted in terms of dimerization of the dye molecules and of the different hydration that D 2 O induces. The effects of dissolved gases on the spectral properties of BTB is studied. Complete removal of dissolved gas is achieved. Surprising effects on the UV–vis spectra emerged. After degassing solutions, gases were re-admitted via bubbling. The gases He, Ar, N 2 , CO 2 and CH 4 .were studied. The effects can be explained by presence or absence of nano- and microbubbles of gas in the solution. These allow formation of dimers and multiple association via adsorption and so affect the spectral properties of the dye molecules." @default.
- W4293577557 created "2022-08-30" @default.
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- W4293577557 date "2022-11-01" @default.
- W4293577557 modified "2023-10-16" @default.
- W4293577557 title "Ionochromism, solvatochromism and effect of dissolved gases on the spectral properties of bromothymol blue" @default.
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- W4293577557 doi "https://doi.org/10.1016/j.molliq.2022.120196" @default.
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