FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4293646952> ?p ?o ?g. }

• W4293646952 endingPage "104504" @default.
• W4293646952 startingPage "104504" @default.
• W4293646952 abstract "The hydrothermal reduction of CO2 using organic molecules such as alcohols can produce renewable fuels and platform chemicals, such as formic acid (FA). If the process is performed using glucose as reductant, the yield is especially high, because FA is selectively produced both by reduction of CO2 and by degradation of glucose degradation in alkaline hydrothermal media. This article analyzes the origin of formic acid using NaH13CO3 as CO2 source, assisted by HPLC and 13C-NMR to study the origin of FA. Results show that two reactions pathways take place: the first one, at short reaction times, consists on the decomposition of glucose into formic acid and other by-products, achieving low yield to FA-13C, whereas longer reaction times lead to a higher yield to FA-13C. Similarly, temperature plays an important role, being 300°C the optimal. Further reactions were performed using the main by-products of previous reactions (acetic acid, lactic acid, glycolaldehyde and glyceraldehyde) as reductants to understand the reaction mechanisms. Results indicate that the reduction pathway of NaHCO3 take place by oxidation of the by-products rather than by the oxidation of glucose itself, needing long reaction times to achieve significant high ratios of FA-13C/ total FA." @default.
• W4293646952 created "2022-08-30" @default.
• W4293646952 creator A5019076889 @default.
• W4293646952 creator A5019779489 @default.
• W4293646952 creator A5039942951 @default.
• W4293646952 creator A5061991859 @default.
• W4293646952 creator A5068913700 @default.
• W4293646952 creator A5086018248 @default.
• W4293646952 creator A5088965809 @default.
• W4293646952 date "2022-10-01" @default.
• W4293646952 modified "2023-10-18" @default.
• W4293646952 title "Formic acid production by simultaneous hydrothermal CO2 reduction and conversion of glucose and its derivatives" @default.
• W4293646952 cites W1717027242 @default.
• W4293646952 cites W1963853244 @default.
• W4293646952 cites W1973623904 @default.
• W4293646952 cites W1974260391 @default.
• W4293646952 cites W1975173430 @default.
• W4293646952 cites W1975683957 @default.
• W4293646952 cites W1980120482 @default.
• W4293646952 cites W1982236815 @default.
• W4293646952 cites W1983782186 @default.
• W4293646952 cites W1990489057 @default.
• W4293646952 cites W1990560294 @default.
• W4293646952 cites W2006676786 @default.
• W4293646952 cites W2012953867 @default.
• W4293646952 cites W2013264726 @default.
• W4293646952 cites W2013636093 @default.
• W4293646952 cites W2013967805 @default.
• W4293646952 cites W2025479235 @default.
• W4293646952 cites W2025496540 @default.
• W4293646952 cites W2026277606 @default.
• W4293646952 cites W2027228707 @default.
• W4293646952 cites W2033305772 @default.
• W4293646952 cites W2039005956 @default.
• W4293646952 cites W2039362231 @default.
• W4293646952 cites W2046297419 @default.
• W4293646952 cites W2050384579 @default.
• W4293646952 cites W2051469691 @default.
• W4293646952 cites W2060746784 @default.
• W4293646952 cites W2069121950 @default.
• W4293646952 cites W2073759811 @default.
• W4293646952 cites W2089388694 @default.
• W4293646952 cites W2135766784 @default.
• W4293646952 cites W2136808884 @default.
• W4293646952 cites W2152837468 @default.
• W4293646952 cites W2319615030 @default.
• W4293646952 cites W2548722365 @default.
• W4293646952 cites W2565870685 @default.
• W4293646952 cites W2589843319 @default.
• W4293646952 cites W2736640337 @default.
• W4293646952 cites W2751898521 @default.
• W4293646952 cites W2752717972 @default.
• W4293646952 cites W2766231966 @default.
• W4293646952 cites W2783193707 @default.
• W4293646952 cites W2810144288 @default.
• W4293646952 cites W2888207456 @default.
• W4293646952 cites W2892471894 @default.
• W4293646952 cites W2909243695 @default.
• W4293646952 cites W2945286866 @default.
• W4293646952 cites W2980439551 @default.
• W4293646952 cites W2993399274 @default.
• W4293646952 cites W3002322545 @default.
• W4293646952 cites W3090161277 @default.
• W4293646952 cites W3177640514 @default.
• W4293646952 cites W4200162879 @default.
• W4293646952 cites W4229443601 @default.
• W4293646952 cites W4281712991 @default.
• W4293646952 cites W4283277119 @default.
• W4293646952 cites W4293859757 @default.
• W4293646952 doi "https://doi.org/10.1016/j.jtice.2022.104504" @default.
• W4293646952 hasPublicationYear "2022" @default.
• W4293646952 type Work @default.
• W4293646952 citedByCount "2" @default.
• W4293646952 countsByYear W42936469522022 @default.
• W4293646952 countsByYear W42936469522023 @default.
• W4293646952 crossrefType "journal-article" @default.
• W4293646952 hasAuthorship W4293646952A5019076889 @default.
• W4293646952 hasAuthorship W4293646952A5019779489 @default.
• W4293646952 hasAuthorship W4293646952A5039942951 @default.
• W4293646952 hasAuthorship W4293646952A5061991859 @default.
• W4293646952 hasAuthorship W4293646952A5068913700 @default.
• W4293646952 hasAuthorship W4293646952A5086018248 @default.
• W4293646952 hasAuthorship W4293646952A5088965809 @default.
• W4293646952 hasBestOaLocation W42936469521 @default.
• W4293646952 hasConcept C124681953 @default.
• W4293646952 hasConcept C127413603 @default.
• W4293646952 hasConcept C134121241 @default.
• W4293646952 hasConcept C156622251 @default.
• W4293646952 hasConcept C161790260 @default.
• W4293646952 hasConcept C178790620 @default.
• W4293646952 hasConcept C181199279 @default.
• W4293646952 hasConcept C185592680 @default.
• W4293646952 hasConcept C191897082 @default.
• W4293646952 hasConcept C192562407 @default.
• W4293646952 hasConcept C2775920511 @default.
• W4293646952 hasConcept C2776317432 @default.
• W4293646952 hasConcept C2776651935 @default.
• W4293646952 hasConcept C2776673659 @default.

• next