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- W4293733549 abstract "<strong class=journal-contentHeaderColor>Abstract.</strong> Nitrate (NO<span class=inline-formula><sub>3</sub><sup>â</sup>)</span> has been the dominant and the least reduced chemical component of fine particulate matter (PM<span class=inline-formula><sub>2.5</sub>)</span> since the stringent emission controls implemented in China in 2013. The formation pathways of NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> vary seasonally and differ substantially in daytime vs. nighttime. They are affected by precursor emissions, atmospheric oxidation capacity, and meteorological conditions. Understanding NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> formation pathways provides insights for the design of effective emission control strategies to mitigate NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> pollution. In this study, the Community Multiscale Air Quality (CMAQ) model was applied to investigate the impact of regional transport, predominant physical processes, and different formation pathways to NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> and total nitrate (TNO<span class=inline-formula><sub>3</sub></span>, i.e., HNO<span class=inline-formula><sub>3</sub>+</span>âNO<span class=inline-formula><sub>3</sub><sup>â</sup></span>) production in the Yangtze River Delta (YRD) region during the four seasons of 2017. NO<span class=inline-formula><math xmlns=http://www.w3.org/1998/Math/MathML id=M10 display=inline overflow=scroll dspmath=mathml><mrow><msub><mi/><mn mathvariant=normal>3</mn></msub><msup><mi/><mo>-</mo></msup><mo>/</mo></mrow></math><span><svg:svg xmlns:svg=http://www.w3.org/2000/svg width=19pt height=15pt class=svg-formula dspmath=mathimg md5hash=e6dfcde6dca9f8fac556c9cf94b8e71d><svg:image xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=acp-22-12629-2022-ie00001.svg width=19pt height=15pt src=acp-22-12629-2022-ie00001.png/></svg:svg></span></span>PM<span class=inline-formula><sub>2.5</sub></span> and NO<span class=inline-formula><math xmlns=http://www.w3.org/1998/Math/MathML id=M12 display=inline overflow=scroll dspmath=mathml><mrow><msub><mi/><mn mathvariant=normal>3</mn></msub><msup><mi/><mo>-</mo></msup><mo>/</mo></mrow></math><span><svg:svg xmlns:svg=http://www.w3.org/2000/svg width=19pt height=15pt class=svg-formula dspmath=mathimg md5hash=5956030adac49453ed51b30bf416f0a1><svg:image xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=acp-22-12629-2022-ie00002.svg width=19pt height=15pt src=acp-22-12629-2022-ie00002.png/></svg:svg></span></span>TNO<span class=inline-formula><sub>3</sub></span> are the highest in the winter, reaching 21â% and 94â%, respectively. The adjusted gas ratio (adjGRâ<span class=inline-formula>=</span>â([NH<span class=inline-formula><sub>3</sub>]+</span>â[NO<span class=inline-formula><sub>3</sub><sup>â</sup></span>]<span class=inline-formula><math xmlns=http://www.w3.org/1998/Math/MathML id=M17 display=inline overflow=scroll dspmath=mathml><mrow><mo>)</mo><mo>/</mo></mrow></math><span><svg:svg xmlns:svg=http://www.w3.org/2000/svg width=12pt height=14pt class=svg-formula dspmath=mathimg md5hash=8f862b6cd93bd2454cf047049b9a7f52><svg:image xmlns:xlink=http://www.w3.org/1999/xlink xlink:href=acp-22-12629-2022-ie00003.svg width=12pt height=14pt src=acp-22-12629-2022-ie00003.png/></svg:svg></span></span>([HNO<span class=inline-formula><sub>3</sub>]+</span>â[NO<span class=inline-formula><sub>3</sub><sup>â</sup></span>])) in the YRD is generally greater than 2 in the four seasons across most areas in the YRD, indicating that YRD is mostly in the NH<span class=inline-formula><sub>3</sub></span>-rich regime and that NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> is limited by HNO<span class=inline-formula><sub>3</sub></span> formation. Local emissions and regional transportation contribute to NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> concentrations throughout the YRD region by 50â%â62â% and 38â%â50â%, respectively. The majority of the regional transport of NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> concentrations is contributed by indirect transport (i.e., NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> formed by transported precursors reacting with local precursors). Aerosol (AERO, including condensation, coagulation, new particle formation, and aerosol growth) processes are the dominant source of NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> formation. In summer, NO<span class=inline-formula><sub>3</sub><sup>â</sup></span> formation is dominated by AERO and total transport (TRAN, sum of horizontal and vertical transport) processes. The OHâ<span class=inline-formula>+</span>âNO<span class=inline-formula><sub>2</sub></span> pathway contributes to 60â%â83â% of the TNO<span class=inline-formula><sub>3</sub></span> production, and the N<span class=inline-formula><sub>2</sub></span>O<span class=inline-formula><sub>5</sub></span> heterogeneous (HETÂ N<span class=inline-formula><sub>2</sub></span>O<span class=inline-formula><sub>5</sub>)</span> pathway contributes to 10â%â36â% in the YRD region. HETÂ N<span class=inline-formula><sub>2</sub></span>O<span class=inline-formula><sub>5</sub></span> contribution becomes more important in cold seasons than warm seasons. Within the planetary boundary layer in Shanghai, the TNO<span class=inline-formula><sub>3</sub></span> production is dominated by the OHâ<span class=inline-formula>+</span>âNO<span class=inline-formula><sub>2</sub></span> pathway during the day (98â%) in the summer and spring and by the HETÂ N<span class=inline-formula><sub>2</sub></span>O<span class=inline-formula><sub>5</sub></span> pathway during the night (61â%) in the winter. Local contributions dominate the OHâ<span class=inline-formula>+</span>âNO<span class=inline-formula><sub>2</sub></span> pathway for TNO<span class=inline-formula><sub>3</sub></span> production during the day, while indirect transport dominates the HETÂ N<span class=inline-formula><sub>2</sub></span>O<span class=inline-formula><sub>5</sub></span> pathway at night." @default.
- W4293733549 created "2022-08-31" @default.
- W4293733549 creator A5001612776 @default.
- W4293733549 date "2022-08-30" @default.
- W4293733549 modified "2023-10-14" @default.
- W4293733549 title "Reply on RC2" @default.
- W4293733549 doi "https://doi.org/10.5194/acp-2022-426-ac2" @default.
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