Matches in SemOpenAlex for { <https://semopenalex.org/work/W4293762942> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W4293762942 abstract "Direct C-H bond functionalization is a useful strategy for the straightforward formation of C-C and C-Heteroatom bonds. In the present work, a unique approach for the challenging electrophilic Au-catalyzed alpha-C-H bond functionalization of tertiary amines is presented. Electronic, steric and conformational synergistic effects exerted by the use of a malonate unit in the substrate were key to the success of this transformation. This new reactivity was applied to the synthesis of tetrahydro-g-carboline products which, under oxidative conditions, could be converted into valuable structural motifs found in bioactive alkaloid natural products" @default.
- W4293762942 created "2022-08-31" @default.
- W4293762942 creator A5036079475 @default.
- W4293762942 creator A5040916112 @default.
- W4293762942 creator A5076670951 @default.
- W4293762942 creator A5076705017 @default.
- W4293762942 creator A5089179159 @default.
- W4293762942 date "2022-08-31" @default.
- W4293762942 modified "2023-09-26" @default.
- W4293762942 title "Steric, Electronic and Conformational Synergistic Effects in the Au(I)-catalyzed alpha-C-H Bond Functionalization of Tertiary Amines" @default.
- W4293762942 doi "https://doi.org/10.26434/chemrxiv-2022-l2mlb" @default.
- W4293762942 hasPublicationYear "2022" @default.
- W4293762942 type Work @default.
- W4293762942 citedByCount "0" @default.
- W4293762942 crossrefType "posted-content" @default.
- W4293762942 hasAuthorship W4293762942A5036079475 @default.
- W4293762942 hasAuthorship W4293762942A5040916112 @default.
- W4293762942 hasAuthorship W4293762942A5076670951 @default.
- W4293762942 hasAuthorship W4293762942A5076705017 @default.
- W4293762942 hasAuthorship W4293762942A5089179159 @default.
- W4293762942 hasBestOaLocation W42937629421 @default.
- W4293762942 hasConcept C115537861 @default.
- W4293762942 hasConcept C142724271 @default.
- W4293762942 hasConcept C147789679 @default.
- W4293762942 hasConcept C161790260 @default.
- W4293762942 hasConcept C178790620 @default.
- W4293762942 hasConcept C185592680 @default.
- W4293762942 hasConcept C201194858 @default.
- W4293762942 hasConcept C204787440 @default.
- W4293762942 hasConcept C20950531 @default.
- W4293762942 hasConcept C21951064 @default.
- W4293762942 hasConcept C2776910235 @default.
- W4293762942 hasConcept C2780378348 @default.
- W4293762942 hasConcept C50027330 @default.
- W4293762942 hasConcept C71240020 @default.
- W4293762942 hasConcept C71924100 @default.
- W4293762942 hasConceptScore W4293762942C115537861 @default.
- W4293762942 hasConceptScore W4293762942C142724271 @default.
- W4293762942 hasConceptScore W4293762942C147789679 @default.
- W4293762942 hasConceptScore W4293762942C161790260 @default.
- W4293762942 hasConceptScore W4293762942C178790620 @default.
- W4293762942 hasConceptScore W4293762942C185592680 @default.
- W4293762942 hasConceptScore W4293762942C201194858 @default.
- W4293762942 hasConceptScore W4293762942C204787440 @default.
- W4293762942 hasConceptScore W4293762942C20950531 @default.
- W4293762942 hasConceptScore W4293762942C21951064 @default.
- W4293762942 hasConceptScore W4293762942C2776910235 @default.
- W4293762942 hasConceptScore W4293762942C2780378348 @default.
- W4293762942 hasConceptScore W4293762942C50027330 @default.
- W4293762942 hasConceptScore W4293762942C71240020 @default.
- W4293762942 hasConceptScore W4293762942C71924100 @default.
- W4293762942 hasLocation W42937629421 @default.
- W4293762942 hasOpenAccess W4293762942 @default.
- W4293762942 hasPrimaryLocation W42937629421 @default.
- W4293762942 hasRelatedWork W1531631192 @default.
- W4293762942 hasRelatedWork W1965060191 @default.
- W4293762942 hasRelatedWork W2014028079 @default.
- W4293762942 hasRelatedWork W2022852064 @default.
- W4293762942 hasRelatedWork W2031172126 @default.
- W4293762942 hasRelatedWork W2032372192 @default.
- W4293762942 hasRelatedWork W2950290979 @default.
- W4293762942 hasRelatedWork W2950925905 @default.
- W4293762942 hasRelatedWork W2950937524 @default.
- W4293762942 hasRelatedWork W4232082472 @default.
- W4293762942 isParatext "false" @default.
- W4293762942 isRetracted "false" @default.
- W4293762942 workType "article" @default.