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- W4293764405 abstract "By taking the advantage of the semi-rigidity of acylamide group, a new case of non-interpenetrated pcu-type Metal−Organic Polyhedral [Cu6(DCPB)3(H2O)6]n·x(solv), HHU-9, was successfully synthesized. In this case, the length decreases of the acylamide-inserted linkers induced by their semi-rigidity triggered the contraction of the cross-shaped channels from 8.23 Å to 6.34 Å, which prevents a second framework from sitting in. Meanwhile, the structure instability of HHU-9 caused by the configuration changes of linkers was directly evidenced by both single-crystal structures and PXRD patterns. In spite of this, HHU-9 still shows selective CO2 adsorption towards N2 and CH4." @default.
- W4293764405 created "2022-08-31" @default.
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- W4293764405 date "2022-11-01" @default.
- W4293764405 modified "2023-10-13" @default.
- W4293764405 title "Avoiding interpenetration by the contraction of acylamide-inserted linker for the construction of A pcu-type Metal-Organic Polyhedral" @default.
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- W4293764405 doi "https://doi.org/10.1016/j.jssc.2022.123519" @default.
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