Matches in SemOpenAlex for { <https://semopenalex.org/work/W4293776457> ?p ?o ?g. }
- W4293776457 abstract "Macrocyclic hosts with a well-defined cavity are particularly appealing for supramolecular chemistry, but they are still rare. In this research, we reported a new class of macrocyclic hosts, namely methylene-bridged naphthotubes, with well-defined cavities. They were synthesized through TFA-catalyzed Friedel-Crafts reactions between alkoxy-substituted bisnaphthalenes and paraformaldehyde. A configurational selection was observed. Three-membered macrocycles possess a single cavity, while four-membered macrocycles adopt a double-cavity conformation or a self-filling conformation depending on the alkoxy length. The small homologue shows quite strong binding affinities (up to 108 M-1 ) to organic cations, which is better than structurally similar but flexible macrocycles. This demonstrates the advantage of a well-defined cavity in molecular recognition. Moreover, these naphthotubes can be used as chirality sensors for chiral organic cations through different chirality transfer mechanisms." @default.
- W4293776457 created "2022-08-31" @default.
- W4293776457 creator A5026002821 @default.
- W4293776457 creator A5032795264 @default.
- W4293776457 creator A5062688449 @default.
- W4293776457 creator A5071464070 @default.
- W4293776457 creator A5087709746 @default.
- W4293776457 date "2022-09-12" @default.
- W4293776457 modified "2023-10-14" @default.
- W4293776457 title "Synthesis, Configurational Analysis, Molecular Recognition and Chirality Sensing of Methylene‐Bridged Naphthotubes" @default.
- W4293776457 cites W2040437294 @default.
- W4293776457 cites W2045288781 @default.
- W4293776457 cites W2048225440 @default.
- W4293776457 cites W2057689723 @default.
- W4293776457 cites W2066358970 @default.
- W4293776457 cites W2088252867 @default.
- W4293776457 cites W2095864742 @default.
- W4293776457 cites W2102107801 @default.
- W4293776457 cites W2120612993 @default.
- W4293776457 cites W2124860710 @default.
- W4293776457 cites W2150223648 @default.
- W4293776457 cites W2287105213 @default.
- W4293776457 cites W2298008471 @default.
- W4293776457 cites W2298576872 @default.
- W4293776457 cites W2303660569 @default.
- W4293776457 cites W2326237485 @default.
- W4293776457 cites W2415889985 @default.
- W4293776457 cites W2462928535 @default.
- W4293776457 cites W2482587427 @default.
- W4293776457 cites W2498629009 @default.
- W4293776457 cites W2515430482 @default.
- W4293776457 cites W2599186445 @default.
- W4293776457 cites W2626445968 @default.
- W4293776457 cites W2730339277 @default.
- W4293776457 cites W2768396589 @default.
- W4293776457 cites W2773657755 @default.
- W4293776457 cites W2788939364 @default.
- W4293776457 cites W2801223681 @default.
- W4293776457 cites W2807545667 @default.
- W4293776457 cites W2808486687 @default.
- W4293776457 cites W2883527129 @default.
- W4293776457 cites W2888464156 @default.
- W4293776457 cites W2907046543 @default.
- W4293776457 cites W2925943609 @default.
- W4293776457 cites W2944841931 @default.
- W4293776457 cites W2961724301 @default.
- W4293776457 cites W2967655329 @default.
- W4293776457 cites W2969733826 @default.
- W4293776457 cites W2990571218 @default.
- W4293776457 cites W2993273025 @default.
- W4293776457 cites W2995339396 @default.
- W4293776457 cites W2997874760 @default.
- W4293776457 cites W3005572608 @default.
- W4293776457 cites W3013386706 @default.
- W4293776457 cites W3014129512 @default.
- W4293776457 cites W3015857415 @default.
- W4293776457 cites W3030152614 @default.
- W4293776457 cites W3043854355 @default.
- W4293776457 cites W3049446641 @default.
- W4293776457 cites W3084436777 @default.
- W4293776457 cites W3111466443 @default.
- W4293776457 cites W3135623180 @default.
- W4293776457 cites W3137064415 @default.
- W4293776457 cites W3143794341 @default.
- W4293776457 cites W3150791210 @default.
- W4293776457 cites W3166038565 @default.
- W4293776457 cites W3168095555 @default.
- W4293776457 cites W3172954750 @default.
- W4293776457 cites W3186755366 @default.
- W4293776457 cites W3190394576 @default.
- W4293776457 cites W3205274411 @default.
- W4293776457 cites W3208439751 @default.
- W4293776457 cites W3214878640 @default.
- W4293776457 cites W4210690126 @default.
- W4293776457 cites W4211153373 @default.
- W4293776457 cites W4213373616 @default.
- W4293776457 cites W4220811149 @default.
- W4293776457 cites W4220818510 @default.
- W4293776457 cites W4220872620 @default.
- W4293776457 cites W4220928741 @default.
- W4293776457 cites W4221079919 @default.
- W4293776457 cites W4224059382 @default.
- W4293776457 cites W4226084130 @default.
- W4293776457 cites W4230863681 @default.
- W4293776457 cites W4231113741 @default.
- W4293776457 cites W4234456784 @default.
- W4293776457 cites W4234861415 @default.
- W4293776457 cites W4239384560 @default.
- W4293776457 cites W4239635265 @default.
- W4293776457 cites W4239693509 @default.
- W4293776457 cites W4245841721 @default.
- W4293776457 cites W4246737837 @default.
- W4293776457 cites W4249757843 @default.
- W4293776457 cites W4250377106 @default.
- W4293776457 cites W4253432396 @default.
- W4293776457 cites W4253491358 @default.
- W4293776457 cites W4283361413 @default.
- W4293776457 cites W4283836310 @default.
- W4293776457 doi "https://doi.org/10.1002/anie.202211853" @default.
- W4293776457 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36042003" @default.