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- W4293821138 abstract "Semistabilized diazatrienyl anions are generated by the reaction of 2-pyridylarylimines with arylacetylenes in superbase systems MOtBu (M = Li, Na, K)/DMSO at ambient temperature for 15 min. The initial intermediate N-centered propargyl-1,3-diaza-1,3,5-trienyl anions undergo intermolecular cyclization to benzyl imidazopyridine anions (formally [3 + 2] cycloaddition), further intercepting a second molecule of the starting pyridylimines or a proton of medium to afford (Z)-stilbene/imidazopyridine ensembles and benzyl imidazopyridines. The charge distribution in all intermediate anions and their synthetic evolution are consistent with quantum-chemical analysis (B2PLYPD/6-311+G**//B3LYP/6-31+G*)." @default.
- W4293821138 created "2022-08-31" @default.
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- W4293821138 date "2022-08-31" @default.
- W4293821138 modified "2023-10-14" @default.
- W4293821138 title "Semistabilized Diazatrienyl Anions from Pyridine Imines and Acetylenes: An Access to (<i>Z</i>)-Stilbene/Imidazopyridine Ensembles, Benzyl Imidazopyridines, and Beyond" @default.
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- W4293821138 doi "https://doi.org/10.1021/acs.joc.2c01372" @default.
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