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- W4293825680 abstract "Based on the intramolecular E1cB elimination, a novel [4 + 2] cyclization was designed and successfully applied to the asymmetric synthesis of polycyclic compounds which contained both chromane and spirooxindole moieties. In the reaction, regardless of the competitive pathways resulting from multireactive sites of starting materials, products could be obtained in good yields (up to 84%) and with excellent enantioselectivities (most 98 to >99% ee) under the catalysis of a chiral bifunctional thiourea-tertiary amine (1–5 mol %)." @default.
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- W4293825680 date "2022-08-18" @default.
- W4293825680 modified "2023-10-18" @default.
- W4293825680 title "Asymmetric Organocatalytic Access to Spiro-fused Heterocyclic Compounds: E1cB Elimination Mediates Formal [4 + 2] Annulation" @default.
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- W4293825680 doi "https://doi.org/10.1021/acs.orglett.2c02435" @default.
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