FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4294129679> ?p ?o ?g. }

• W4294129679 abstract "Environmental problem caused by carbon emission is of widespread concern. Involving CO2 as C1 resource into chemical synthesis is one of the most attractive ways for carbon recycling. Herein, the first example of host-guest composites featuring metal-organic framework (MOF)-encapsulated binuclear N-heterocyclic carbene (NHC) complex, Co2 @MIL101, was developed with the molecularly dispersed [Co(IPr)Br]2 (μ-Br)2 (Co2 ) loading in the cage of MIL-101(Cr) via a ligand-in-dimer-trap strategy, which was comprehensively investigated through various techniques including synchrotron X-ray absorption, electron microscopy, X-ray diffraction, solid-state nuclear magnetic resonance spectroscopy, and others. The noble-metal-free double-sites catalyst Co2 @MIL101 exhibited promising stability, activity, efficiency, reusability, and substrate adaptability for converting CO2 into various formamides with amines and hydrosilanes and achieved the best performance for one of the most useful formamides, N-methyl-N-phenylformamide (MFA), among the recyclable catalysts at ambient conditions, providing a reliable approach to successfully unify the advantages of both homo- and heterogeneous catalysts. Density functional theory calculations were applied to illustrate the superior activity of the binuclear NHC complex center as double-sites catalyst toward the activation of CO2 ." @default.
• W4294129679 created "2022-09-02" @default.
• W4294129679 creator A5021720931 @default.
• W4294129679 creator A5025048556 @default.
• W4294129679 creator A5076409244 @default.
• W4294129679 creator A5089892559 @default.
• W4294129679 date "2022-09-01" @default.
• W4294129679 modified "2023-10-09" @default.
• W4294129679 title "MOF‐Incorporated Binuclear N‐Heterocyclic Carbene‐Cobalt Catalyst for Efficient Conversion of CO₂ to Formamides" @default.
• W4294129679 cites W1812339079 @default.
• W4294129679 cites W1989531234 @default.
• W4294129679 cites W2007661885 @default.
• W4294129679 cites W2022963420 @default.
• W4294129679 cites W2023272504 @default.
• W4294129679 cites W2068617439 @default.
• W4294129679 cites W2071246095 @default.
• W4294129679 cites W2086957099 @default.
• W4294129679 cites W2091284822 @default.
• W4294129679 cites W2091958922 @default.
• W4294129679 cites W2094642658 @default.
• W4294129679 cites W2096248136 @default.
• W4294129679 cites W2096411479 @default.
• W4294129679 cites W2106522547 @default.
• W4294129679 cites W2110154495 @default.
• W4294129679 cites W2110659651 @default.
• W4294129679 cites W2136726885 @default.
• W4294129679 cites W2145277245 @default.
• W4294129679 cites W2155810941 @default.
• W4294129679 cites W2159785986 @default.
• W4294129679 cites W2164571086 @default.
• W4294129679 cites W2166449173 @default.
• W4294129679 cites W2171836549 @default.
• W4294129679 cites W2192853384 @default.
• W4294129679 cites W2313880395 @default.
• W4294129679 cites W2316739273 @default.
• W4294129679 cites W2321291366 @default.
• W4294129679 cites W2344956874 @default.
• W4294129679 cites W2418017613 @default.
• W4294129679 cites W2477679257 @default.
• W4294129679 cites W2502147300 @default.
• W4294129679 cites W2512697096 @default.
• W4294129679 cites W2528956049 @default.
• W4294129679 cites W2552827075 @default.
• W4294129679 cites W2590332333 @default.
• W4294129679 cites W2624049315 @default.
• W4294129679 cites W2728984380 @default.
• W4294129679 cites W2739918986 @default.
• W4294129679 cites W2779319614 @default.
• W4294129679 cites W2782016597 @default.
• W4294129679 cites W2791309912 @default.
• W4294129679 cites W2794728674 @default.
• W4294129679 cites W2806136383 @default.
• W4294129679 cites W2885802382 @default.
• W4294129679 cites W2902903972 @default.
• W4294129679 cites W2905299148 @default.
• W4294129679 cites W2907758246 @default.
• W4294129679 cites W2914299958 @default.
• W4294129679 cites W2926036315 @default.
• W4294129679 cites W2949697738 @default.
• W4294129679 cites W2959668253 @default.
• W4294129679 cites W2965069462 @default.
• W4294129679 cites W2965398658 @default.
• W4294129679 cites W2966686337 @default.
• W4294129679 cites W2968033226 @default.
• W4294129679 cites W2978553428 @default.
• W4294129679 cites W2986231987 @default.
• W4294129679 cites W2990950642 @default.
• W4294129679 cites W3010856216 @default.
• W4294129679 cites W3018305286 @default.
• W4294129679 cites W3048536584 @default.
• W4294129679 cites W3084523186 @default.
• W4294129679 cites W3090668976 @default.
• W4294129679 cites W3107552450 @default.
• W4294129679 cites W3112581906 @default.
• W4294129679 cites W3113223809 @default.
• W4294129679 cites W3120625962 @default.
• W4294129679 cites W3128902905 @default.
• W4294129679 cites W3134155491 @default.
• W4294129679 cites W3153990953 @default.
• W4294129679 cites W3158142694 @default.
• W4294129679 cites W3164826510 @default.
• W4294129679 cites W3165127355 @default.
• W4294129679 cites W3175713995 @default.
• W4294129679 cites W3185926922 @default.
• W4294129679 cites W3187888768 @default.
• W4294129679 cites W3193568471 @default.
• W4294129679 cites W3194966817 @default.
• W4294129679 cites W3196218432 @default.
• W4294129679 cites W3212358321 @default.
• W4294129679 cites W4205239647 @default.
• W4294129679 cites W4206631307 @default.
• W4294129679 cites W4206897972 @default.
• W4294129679 cites W4207051011 @default.
• W4294129679 cites W4211207668 @default.
• W4294129679 cites W4214594228 @default.
• W4294129679 cites W4225512312 @default.
• W4294129679 cites W4233444316 @default.
• W4294129679 cites W4234402712 @default.
• W4294129679 cites W4234659033 @default.
• W4294129679 cites W4236845392 @default.

• next