Matches in SemOpenAlex for { <https://semopenalex.org/work/W4294193211> ?p ?o ?g. }
- W4294193211 endingPage "136255" @default.
- W4294193211 startingPage "136255" @default.
- W4294193211 abstract "Developing new catalysts for efficient degradation of micropollutants in water is of significant importance in advanced oxidation processes (AOPs). Herein, TiO2/C coated Co3O4 nanocages (Co3O4@TiO2/C) were synthesized and their performance on micropollutants degradation was evaluated. Specifically, cobalt-based Zeolitic imidazolate framework (ZIF-67) coated by a thin layer of titanium species and polydopamine (PDA) was used as a precursor for the preparation of Co3O4@TiO2/C by two-step calcination. The catalytic performance of peroxymonosulfate (PMS) activation towards the degradation of organic pollutants was investigated by using atrazine (ATZ) and Bisphenol A (BPA) as typical micropollutants. The efficiency and the effect of TiO2/C shell on the as-synthesized catalyst were analyzed by comparing Co3O4 derived from ZIF-67 and Co3O4/C derived from ZIF-67/PDA. ATZ degradation results showed that the Co3O4@TiO2/C catalyst was the most efficient for catalytic oxidation when 99.5% of ATZ was removed within 4 min, which is 57.5% and 74.6% faster than that of Co3O4@C and Co3O4, respectively. The enhanced performance of Co3O4@TiO2/C is attributed to their unique nanocages structure and improved specific surface area. The catalysis mechanisms and ATZ degradation pathways were presented based on the results of electron paramagnetic resonance (EPR), XPS, and LC-MS analysis. Our results might have added to the design of heterogeneous catalysts of large surface area for efficient PMS activation in AOPs." @default.
- W4294193211 created "2022-09-02" @default.
- W4294193211 creator A5027584660 @default.
- W4294193211 creator A5044082813 @default.
- W4294193211 creator A5046996256 @default.
- W4294193211 creator A5049341927 @default.
- W4294193211 creator A5053498673 @default.
- W4294193211 creator A5063159226 @default.
- W4294193211 date "2022-12-01" @default.
- W4294193211 modified "2023-10-18" @default.
- W4294193211 title "TiO2/C coated Co3O4 nanocages for peroxymonosulfate activation towards efficient degradation of organic pollutants" @default.
- W4294193211 cites W2000082462 @default.
- W4294193211 cites W2010479638 @default.
- W4294193211 cites W2033612153 @default.
- W4294193211 cites W2035429631 @default.
- W4294193211 cites W2042049555 @default.
- W4294193211 cites W2054759372 @default.
- W4294193211 cites W2072268137 @default.
- W4294193211 cites W2080795088 @default.
- W4294193211 cites W2135729805 @default.
- W4294193211 cites W2287966185 @default.
- W4294193211 cites W2337743982 @default.
- W4294193211 cites W2512286790 @default.
- W4294193211 cites W2513857983 @default.
- W4294193211 cites W2534737939 @default.
- W4294193211 cites W2551751767 @default.
- W4294193211 cites W2599557236 @default.
- W4294193211 cites W2726479470 @default.
- W4294193211 cites W2744151790 @default.
- W4294193211 cites W2761517321 @default.
- W4294193211 cites W2769560688 @default.
- W4294193211 cites W2770349822 @default.
- W4294193211 cites W2773150701 @default.
- W4294193211 cites W2793900155 @default.
- W4294193211 cites W2801208774 @default.
- W4294193211 cites W2809656826 @default.
- W4294193211 cites W2884772140 @default.
- W4294193211 cites W2888150121 @default.
- W4294193211 cites W2916822676 @default.
- W4294193211 cites W2921495635 @default.
- W4294193211 cites W2926031863 @default.
- W4294193211 cites W2937132408 @default.
- W4294193211 cites W2942736639 @default.
- W4294193211 cites W2949760643 @default.
- W4294193211 cites W2965597652 @default.
- W4294193211 cites W2971249378 @default.
- W4294193211 cites W2973076841 @default.
- W4294193211 cites W2979548319 @default.
- W4294193211 cites W2981153395 @default.
- W4294193211 cites W3018987224 @default.
- W4294193211 cites W3028395544 @default.
- W4294193211 cites W3091411727 @default.
- W4294193211 cites W3092691791 @default.
- W4294193211 cites W3113467784 @default.
- W4294193211 cites W3164879321 @default.
- W4294193211 cites W3169193305 @default.
- W4294193211 cites W3170982982 @default.
- W4294193211 cites W3180483171 @default.
- W4294193211 cites W376699256 @default.
- W4294193211 doi "https://doi.org/10.1016/j.chemosphere.2022.136255" @default.
- W4294193211 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36064019" @default.
- W4294193211 hasPublicationYear "2022" @default.
- W4294193211 type Work @default.
- W4294193211 citedByCount "3" @default.
- W4294193211 countsByYear W42941932112023 @default.
- W4294193211 crossrefType "journal-article" @default.
- W4294193211 hasAuthorship W4294193211A5027584660 @default.
- W4294193211 hasAuthorship W4294193211A5044082813 @default.
- W4294193211 hasAuthorship W4294193211A5046996256 @default.
- W4294193211 hasAuthorship W4294193211A5049341927 @default.
- W4294193211 hasAuthorship W4294193211A5053498673 @default.
- W4294193211 hasAuthorship W4294193211A5063159226 @default.
- W4294193211 hasConcept C121332964 @default.
- W4294193211 hasConcept C127413603 @default.
- W4294193211 hasConcept C128355301 @default.
- W4294193211 hasConcept C13965031 @default.
- W4294193211 hasConcept C150394285 @default.
- W4294193211 hasConcept C150581940 @default.
- W4294193211 hasConcept C161790260 @default.
- W4294193211 hasConcept C166595027 @default.
- W4294193211 hasConcept C175708663 @default.
- W4294193211 hasConcept C178790620 @default.
- W4294193211 hasConcept C179104552 @default.
- W4294193211 hasConcept C179366358 @default.
- W4294193211 hasConcept C185592680 @default.
- W4294193211 hasConcept C187961010 @default.
- W4294193211 hasConcept C2779679103 @default.
- W4294193211 hasConcept C2779684741 @default.
- W4294193211 hasConcept C2780596747 @default.
- W4294193211 hasConcept C27983359 @default.
- W4294193211 hasConcept C41008148 @default.
- W4294193211 hasConcept C42360764 @default.
- W4294193211 hasConcept C46141821 @default.
- W4294193211 hasConcept C515602321 @default.
- W4294193211 hasConcept C7082614 @default.
- W4294193211 hasConcept C76155785 @default.
- W4294193211 hasConceptScore W4294193211C121332964 @default.
- W4294193211 hasConceptScore W4294193211C127413603 @default.