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- W4294770454 abstract "We report a copper-catalyzed alkynylation of azadipeptides using ethynylbenziodoxolone (EBX) reagents. Nonsymmetrical ynehydrazides could be obtained in 25–97% yield using azaglycine derivatives as nucleophiles. The transformation is compatible with most functional groups naturally occurring on amino acid side chains and allows the transfer of silyl-, alkyl-, and aryl-substituted alkynes. The obtained α-alkynyl azaglycine products could be further functionalized by nucleophilic attack or cycloaddition on the triple bond." @default.
- W4294770454 created "2022-09-06" @default.
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- W4294770454 date "2022-09-06" @default.
- W4294770454 modified "2023-09-30" @default.
- W4294770454 title "Copper-Catalyzed Alkynylation of Hydrazides: An Easy Access to Functionalized Azadipeptides" @default.
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- W4294770454 doi "https://doi.org/10.1021/acs.orglett.2c02625" @default.
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