Matches in SemOpenAlex for { <https://semopenalex.org/work/W4294797013> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W4294797013 abstract "Abstract Modeling of eight mechanisms for the incorporation of Ti 4+ and Cr 3+ impurity components into phlogopite was carried out by a semi-empirical method using the GULP (General Utility Lattice Program) software. The calculation of thermodynamic mixing properties in the range of 1–7 GPa and 373–1573 K and the analysis of the structure geometry for the simulated solid solutions provided the following energy-preferred schemes of isomorphic substitution: VI (Mg 2+ ) + 2 IV (Si 4+ ) = VI (Ti 4+ ) + 2 IV (Al 3+ ) and VI (Mg 2+ ) + 2 IV (Al 3+ ) = VI (□)+ 2 IV (Ti 4+ ), VI (Mg 2+ ) + IV (Si 4+ ) = VI (Cr 3+ ) + IV (Al 3+ ), and 3 VI (Mg 2+ ) = VI (Al 3+ ) + VI (Cr 3+ ) + VI (□). It is shown the scheme 2 VI (Mg 2+ ) = VI (Ti 4+ ) + VI (□) illustrating entrance of Ti with the formation of a vacancy is realized in the case of microconcentrations of Ti only. Accumulation of high Ti contents associates with the formation of a vacancy in the octahedral site. This provides incorporation of Ti via the schemes VI (Mg 2+ ) + 2 IV (Al 3+ ) = VI (□)+ 2 IV (Ti 4+ ) and (Mg,Fe 2+ ) + 2OH - = Ti 4+ + 2O 2- only. It is shown that incorporation of high Cr concentrations (>5.5 wt % Cr 2 O 3 ) is accompanied by an increase in the number of vacancies in the octahedral site with an increase in the proportion of the dioctahedral component K(Al,Cr,□)AlSi 3 O 10 (OH) 2 ." @default.
- W4294797013 created "2022-09-06" @default.
- W4294797013 creator A5024667059 @default.
- W4294797013 creator A5036678375 @default.
- W4294797013 creator A5088375348 @default.
- W4294797013 date "2022-09-06" @default.
- W4294797013 modified "2023-10-18" @default.
- W4294797013 title "Mechanisms and Conditions of Ti and Cr Incorporation in Mantle Phlogopite: The Results of Atomistic Simulation" @default.
- W4294797013 cites W1974544384 @default.
- W4294797013 cites W1977181575 @default.
- W4294797013 cites W1984381413 @default.
- W4294797013 cites W1989519861 @default.
- W4294797013 cites W1998313003 @default.
- W4294797013 cites W2003601722 @default.
- W4294797013 cites W2015246848 @default.
- W4294797013 cites W2020682222 @default.
- W4294797013 cites W2028317113 @default.
- W4294797013 cites W2032585744 @default.
- W4294797013 cites W2035283003 @default.
- W4294797013 cites W2040262687 @default.
- W4294797013 cites W2041124629 @default.
- W4294797013 cites W2047406392 @default.
- W4294797013 cites W2053135892 @default.
- W4294797013 cites W2054030114 @default.
- W4294797013 cites W2055933456 @default.
- W4294797013 cites W2057502998 @default.
- W4294797013 cites W2066052703 @default.
- W4294797013 cites W2081507714 @default.
- W4294797013 cites W2082827421 @default.
- W4294797013 cites W2087427140 @default.
- W4294797013 cites W2094426689 @default.
- W4294797013 cites W2112842178 @default.
- W4294797013 cites W2115864365 @default.
- W4294797013 cites W2178718305 @default.
- W4294797013 cites W2308153341 @default.
- W4294797013 cites W2321796051 @default.
- W4294797013 cites W2330846769 @default.
- W4294797013 cites W2342558725 @default.
- W4294797013 cites W2489238667 @default.
- W4294797013 cites W2509903328 @default.
- W4294797013 cites W2532514397 @default.
- W4294797013 cites W2955584243 @default.
- W4294797013 cites W2982873563 @default.
- W4294797013 cites W3082939918 @default.
- W4294797013 cites W4234215135 @default.
- W4294797013 doi "https://doi.org/10.21203/rs.3.rs-1990265/v1" @default.
- W4294797013 hasPublicationYear "2022" @default.
- W4294797013 type Work @default.
- W4294797013 citedByCount "0" @default.
- W4294797013 crossrefType "posted-content" @default.
- W4294797013 hasAuthorship W4294797013A5024667059 @default.
- W4294797013 hasAuthorship W4294797013A5036678375 @default.
- W4294797013 hasAuthorship W4294797013A5088375348 @default.
- W4294797013 hasBestOaLocation W42947970131 @default.
- W4294797013 hasConcept C114221277 @default.
- W4294797013 hasConcept C115624301 @default.
- W4294797013 hasConcept C121332964 @default.
- W4294797013 hasConcept C138999460 @default.
- W4294797013 hasConcept C178790620 @default.
- W4294797013 hasConcept C185592680 @default.
- W4294797013 hasConcept C191897082 @default.
- W4294797013 hasConcept C192562407 @default.
- W4294797013 hasConcept C198819137 @default.
- W4294797013 hasConcept C2778882853 @default.
- W4294797013 hasConcept C67236022 @default.
- W4294797013 hasConcept C71987851 @default.
- W4294797013 hasConcept C8010536 @default.
- W4294797013 hasConcept C8058405 @default.
- W4294797013 hasConceptScore W4294797013C114221277 @default.
- W4294797013 hasConceptScore W4294797013C115624301 @default.
- W4294797013 hasConceptScore W4294797013C121332964 @default.
- W4294797013 hasConceptScore W4294797013C138999460 @default.
- W4294797013 hasConceptScore W4294797013C178790620 @default.
- W4294797013 hasConceptScore W4294797013C185592680 @default.
- W4294797013 hasConceptScore W4294797013C191897082 @default.
- W4294797013 hasConceptScore W4294797013C192562407 @default.
- W4294797013 hasConceptScore W4294797013C198819137 @default.
- W4294797013 hasConceptScore W4294797013C2778882853 @default.
- W4294797013 hasConceptScore W4294797013C67236022 @default.
- W4294797013 hasConceptScore W4294797013C71987851 @default.
- W4294797013 hasConceptScore W4294797013C8010536 @default.
- W4294797013 hasConceptScore W4294797013C8058405 @default.
- W4294797013 hasLocation W42947970131 @default.
- W4294797013 hasOpenAccess W4294797013 @default.
- W4294797013 hasPrimaryLocation W42947970131 @default.
- W4294797013 hasRelatedWork W1993300863 @default.
- W4294797013 hasRelatedWork W1998357897 @default.
- W4294797013 hasRelatedWork W2003687884 @default.
- W4294797013 hasRelatedWork W2037313412 @default.
- W4294797013 hasRelatedWork W2062693162 @default.
- W4294797013 hasRelatedWork W2184965795 @default.
- W4294797013 hasRelatedWork W2318231537 @default.
- W4294797013 hasRelatedWork W2530872012 @default.
- W4294797013 hasRelatedWork W2603611415 @default.
- W4294797013 hasRelatedWork W2182428551 @default.
- W4294797013 isParatext "false" @default.
- W4294797013 isRetracted "false" @default.
- W4294797013 workType "article" @default.