Matches in SemOpenAlex for { <https://semopenalex.org/work/W4294865370> ?p ?o ?g. }
- W4294865370 endingPage "22329" @default.
- W4294865370 startingPage "22319" @default.
- W4294865370 abstract "Chemical bond lengths and angles are characteristic structural parameters of a molecule. Similarly, the frequencies of the vibrational modes and the NMR chemical shifts are unique chemical fingerprints specific to a compound. These are the basic parameters describing newly obtained compounds and enabling their identification. Intramolecular hydrogen bonding significantly influences the physicochemical properties of macrocyclic compounds with a porphyrin-like structure. This work presents the verification for correlations between geometric and spectroscopic parameters related to hydrogen bonds in this type of macrocyclic compounds. In particular, such relationships were investigated for a large group of porphyrin, porphycene, and dibenzotetraaza[14]annulene derivatives and a group of other macrocycles with similar structure. A very strong linear correlation was found only between the vibrational frequencies of the NH groups involved in a hydrogen bond and the length of this bond, which applied to all macrocyclic compounds of this type. Several other relationships were found between spectroscopic (IR, Raman, NMR) and geometric (X-ray) parameters, highlighting differences and similarities between different families of macrocycles. Apart from providing a better understanding of the nature of hydrogen bonds and their characteristics in porphyrin-like macrocyclic compounds, these relationships will facilitate the identification of new macrocycles and the extrapolation of their spectroscopic properties." @default.
- W4294865370 created "2022-09-07" @default.
- W4294865370 creator A5048937098 @default.
- W4294865370 creator A5080556290 @default.
- W4294865370 date "2022-01-01" @default.
- W4294865370 modified "2023-09-30" @default.
- W4294865370 title "Searching for correlations between geometric and spectroscopic parameters of intramolecular hydrogen bonds in porphyrin-like macrocycles" @default.
- W4294865370 cites W1492476323 @default.
- W4294865370 cites W1505914198 @default.
- W4294865370 cites W1568794184 @default.
- W4294865370 cites W1665007207 @default.
- W4294865370 cites W1977054502 @default.
- W4294865370 cites W1979087321 @default.
- W4294865370 cites W1996610300 @default.
- W4294865370 cites W2004752849 @default.
- W4294865370 cites W2006680522 @default.
- W4294865370 cites W2008283039 @default.
- W4294865370 cites W2013051798 @default.
- W4294865370 cites W2016521621 @default.
- W4294865370 cites W2018132271 @default.
- W4294865370 cites W2023088551 @default.
- W4294865370 cites W2026217202 @default.
- W4294865370 cites W2029406559 @default.
- W4294865370 cites W2029576712 @default.
- W4294865370 cites W2037844274 @default.
- W4294865370 cites W2039245807 @default.
- W4294865370 cites W2042982763 @default.
- W4294865370 cites W2046412723 @default.
- W4294865370 cites W2050449953 @default.
- W4294865370 cites W2058634067 @default.
- W4294865370 cites W2058973852 @default.
- W4294865370 cites W2067011309 @default.
- W4294865370 cites W2070625559 @default.
- W4294865370 cites W2073059073 @default.
- W4294865370 cites W2075878196 @default.
- W4294865370 cites W2079794007 @default.
- W4294865370 cites W2088062542 @default.
- W4294865370 cites W2092700658 @default.
- W4294865370 cites W2093969133 @default.
- W4294865370 cites W2094160169 @default.
- W4294865370 cites W2095293317 @default.
- W4294865370 cites W2096608136 @default.
- W4294865370 cites W2099316004 @default.
- W4294865370 cites W2100771651 @default.
- W4294865370 cites W2125328362 @default.
- W4294865370 cites W2136545558 @default.
- W4294865370 cites W2140941134 @default.
- W4294865370 cites W2152764444 @default.
- W4294865370 cites W2156421617 @default.
- W4294865370 cites W2167188767 @default.
- W4294865370 cites W2227975624 @default.
- W4294865370 cites W2234998704 @default.
- W4294865370 cites W2296568969 @default.
- W4294865370 cites W2312471787 @default.
- W4294865370 cites W2316822864 @default.
- W4294865370 cites W2328204822 @default.
- W4294865370 cites W2328263101 @default.
- W4294865370 cites W2403635530 @default.
- W4294865370 cites W2472596221 @default.
- W4294865370 cites W2501164580 @default.
- W4294865370 cites W2532224295 @default.
- W4294865370 cites W2573329358 @default.
- W4294865370 cites W2594817542 @default.
- W4294865370 cites W2602687392 @default.
- W4294865370 cites W2766058838 @default.
- W4294865370 cites W2777213020 @default.
- W4294865370 cites W292689875 @default.
- W4294865370 cites W2949745613 @default.
- W4294865370 cites W3121074538 @default.
- W4294865370 cites W3126632309 @default.
- W4294865370 cites W3142829692 @default.
- W4294865370 cites W3204054654 @default.
- W4294865370 cites W3205919132 @default.
- W4294865370 cites W4230551343 @default.
- W4294865370 cites W4233494337 @default.
- W4294865370 doi "https://doi.org/10.1039/d2cp01195f" @default.
- W4294865370 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36098255" @default.
- W4294865370 hasPublicationYear "2022" @default.
- W4294865370 type Work @default.
- W4294865370 citedByCount "0" @default.
- W4294865370 crossrefType "journal-article" @default.
- W4294865370 hasAuthorship W4294865370A5048937098 @default.
- W4294865370 hasAuthorship W4294865370A5080556290 @default.
- W4294865370 hasBestOaLocation W42948653701 @default.
- W4294865370 hasConcept C103319777 @default.
- W4294865370 hasConcept C111429119 @default.
- W4294865370 hasConcept C112887158 @default.
- W4294865370 hasConcept C120665830 @default.
- W4294865370 hasConcept C121332964 @default.
- W4294865370 hasConcept C132459708 @default.
- W4294865370 hasConcept C134306372 @default.
- W4294865370 hasConcept C147597530 @default.
- W4294865370 hasConcept C147789679 @default.
- W4294865370 hasConcept C178790620 @default.
- W4294865370 hasConcept C185592680 @default.
- W4294865370 hasConcept C20362734 @default.
- W4294865370 hasConcept C2779480358 @default.
- W4294865370 hasConcept C32909587 @default.