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• W4294908248 abstract "Although manganese ions exhibit a rich redox chemistry, redox processes are often accompanied by structural reorganization and a high propensity for ligand substitution, so that no complete structurally characterized manganese(II,III,IV) complex series without significant ligand sphere reorganization akin to the manganese(II,III,IV) oxides exists. We present here the series of pseudo-octahedral homoleptic manganese complexes [Mn(dgpy)2]n+ (n = 2-4) with the adaptable tridentate push-pull ligand 2,6-diguanidylpyridine (dgpy). Mn-N bond lengths and N-Mn-N bond angles change characteristically from n = 2 to n = 4, while the overall [MnN6] coordination sphere is preserved. The manganese(III) complex [Mn(dgpy)2]3+ exhibits a Jahn-Teller elongated octahedron and a negative D = -3.84 cm-1. Concomitantly with the consecutive oxidation of [Mn(dgpy)2]2+ to [Mn(dgpy)2]4+, the optical properties evolve with increasing ligand-to-metal charge transfer character of the absorption bands culminating in the panchromatic absorption of the purple-black manganese(IV) complex [Mn(dgpy)2]4+." @default.
• W4294908248 created "2022-09-07" @default.
• W4294908248 creator A5011496890 @default.
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• W4294908248 date "2022-09-07" @default.
• W4294908248 modified "2023-10-17" @default.
• W4294908248 title "The Full d³–d⁵ Redox Series of Mononuclear Manganese Complexes: Geometries and Electronic Structures of [Mn(dgpy)₂]^<i>n</i>+" @default.
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• W4294908248 doi "https://doi.org/10.1021/acs.inorgchem.2c01680" @default.
• W4294908248 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36070611" @default.
• W4294908248 hasPublicationYear "2022" @default.
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