Matches in SemOpenAlex for { <https://semopenalex.org/work/W4294920342> ?p ?o ?g. }
- W4294920342 endingPage "14741" @default.
- W4294920342 startingPage "14726" @default.
- W4294920342 abstract "The reactions of [HRu3(CO)11]- (1) with M(I) (M = Cu, Ag, and Au) compounds such as [Cu(CH3CN)4][BF4], AgNO3, and Au(Et2S)Cl afford the 2-D molecular alloy clusters [CuRu6(CO)22]- (2), [AgRu6(CO)22]- (3), and [AuRu5(CO)19]- (4), respectively. The reactions of 2-4 with PPh3 result in mixtures of products, among which [Cu2Ru8(CO)26]2- (5), Ru4(CO)12(CuPPh3)4 (6), Ru4(CO)12(AgPPh3)4 (7), Ru(CO)3(PPh3)2 (8), and HRu3(OH)(CO)7(PPh3)3 (9) have been isolated and characterized. The molecular structures of 2-6 and 9 have been determined by single-crystal X-ray diffraction. The metal-metal bonding within 2-5 has been computationally investigated by density functional theory methods. In addition, the [NEt4]+ salts of 2-4 have been tested as catalyst precursors for transfer hydrogenation on the model substrate 4-fluoroacetophenone using iPrOH as a solvent and a hydrogen source." @default.
- W4294920342 created "2022-09-08" @default.
- W4294920342 creator A5001024113 @default.
- W4294920342 creator A5041531483 @default.
- W4294920342 creator A5050423227 @default.
- W4294920342 creator A5055414445 @default.
- W4294920342 creator A5055852692 @default.
- W4294920342 creator A5063568112 @default.
- W4294920342 creator A5073573453 @default.
- W4294920342 date "2022-09-07" @default.
- W4294920342 modified "2023-09-30" @default.
- W4294920342 title "2-D Molecular Alloy Ru–M (M = Cu, Ag, and Au) Carbonyl Clusters: Synthesis, Molecular Structure, Catalysis, and Computational Studies" @default.
- W4294920342 cites W1963547114 @default.
- W4294920342 cites W1969360633 @default.
- W4294920342 cites W1971933722 @default.
- W4294920342 cites W1975982557 @default.
- W4294920342 cites W1985934965 @default.
- W4294920342 cites W1988091937 @default.
- W4294920342 cites W1991740854 @default.
- W4294920342 cites W1996308711 @default.
- W4294920342 cites W1999329768 @default.
- W4294920342 cites W2002572577 @default.
- W4294920342 cites W2015723183 @default.
- W4294920342 cites W2027371854 @default.
- W4294920342 cites W2039559098 @default.
- W4294920342 cites W2040653174 @default.
- W4294920342 cites W2042300815 @default.
- W4294920342 cites W2050488389 @default.
- W4294920342 cites W2058848030 @default.
- W4294920342 cites W2062698002 @default.
- W4294920342 cites W2064715103 @default.
- W4294920342 cites W2067718414 @default.
- W4294920342 cites W2074362665 @default.
- W4294920342 cites W2079521804 @default.
- W4294920342 cites W2083861238 @default.
- W4294920342 cites W2092157292 @default.
- W4294920342 cites W2092265729 @default.
- W4294920342 cites W2096747776 @default.
- W4294920342 cites W2119547517 @default.
- W4294920342 cites W2128863855 @default.
- W4294920342 cites W2132525235 @default.
- W4294920342 cites W2153136744 @default.
- W4294920342 cites W2156257115 @default.
- W4294920342 cites W2169858698 @default.
- W4294920342 cites W2171787578 @default.
- W4294920342 cites W2328340213 @default.
- W4294920342 cites W2329785065 @default.
- W4294920342 cites W2489845635 @default.
- W4294920342 cites W2559821241 @default.
- W4294920342 cites W2575724262 @default.
- W4294920342 cites W2580175397 @default.
- W4294920342 cites W2613456281 @default.
- W4294920342 cites W2739439285 @default.
- W4294920342 cites W2742638984 @default.
- W4294920342 cites W2852424576 @default.
- W4294920342 cites W2913282354 @default.
- W4294920342 cites W2924795774 @default.
- W4294920342 cites W2939570704 @default.
- W4294920342 cites W2949290626 @default.
- W4294920342 cites W3003167515 @default.
- W4294920342 cites W3017901245 @default.
- W4294920342 cites W3029349252 @default.
- W4294920342 cites W3044537240 @default.
- W4294920342 cites W3087240806 @default.
- W4294920342 cites W3091005920 @default.
- W4294920342 cites W3092479292 @default.
- W4294920342 cites W3092623765 @default.
- W4294920342 cites W3094474815 @default.
- W4294920342 cites W3111512562 @default.
- W4294920342 cites W3115049506 @default.
- W4294920342 cites W3128025519 @default.
- W4294920342 cites W3135250112 @default.
- W4294920342 cites W3152535912 @default.
- W4294920342 cites W3161788477 @default.
- W4294920342 cites W3168600296 @default.
- W4294920342 cites W3174914114 @default.
- W4294920342 cites W3182116873 @default.
- W4294920342 cites W3189352315 @default.
- W4294920342 cites W3198734743 @default.
- W4294920342 cites W4200578950 @default.
- W4294920342 cites W4205721985 @default.
- W4294920342 cites W4211236156 @default.
- W4294920342 cites W4214505135 @default.
- W4294920342 doi "https://doi.org/10.1021/acs.inorgchem.2c02099" @default.
- W4294920342 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36069711" @default.
- W4294920342 hasPublicationYear "2022" @default.
- W4294920342 type Work @default.
- W4294920342 citedByCount "2" @default.
- W4294920342 countsByYear W42949203422023 @default.
- W4294920342 crossrefType "journal-article" @default.
- W4294920342 hasAuthorship W4294920342A5001024113 @default.
- W4294920342 hasAuthorship W4294920342A5041531483 @default.
- W4294920342 hasAuthorship W4294920342A5050423227 @default.
- W4294920342 hasAuthorship W4294920342A5055414445 @default.
- W4294920342 hasAuthorship W4294920342A5055852692 @default.
- W4294920342 hasAuthorship W4294920342A5063568112 @default.
- W4294920342 hasAuthorship W4294920342A5073573453 @default.
- W4294920342 hasBestOaLocation W42949203421 @default.