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- W4294927104 endingPage "154801" @default.
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- W4294927104 abstract "Enhancing the electrical conductivity and relieving the volume expansion is essential to boost the lithium storage performance of CoP. Herein, carbon-coated CoP particles are uniformly embedded into N, P, and S triple-doped honeycomb porous carbon ([email protected]) synthesized via a one-step foaming method. In this structure, N, P, and S doping improved the charge transfer kinetics, ion transport capacity, and pseudocapacitance contribution of the [email protected] electrode, respectively. The synergistic effect of the three elements further endows [email protected] with abundant electrochemical reaction sites, optimized pore structure and high electrical conductivity. In addition, the CoP nanoparticles are stably embedded in the pore channels by forming surface chemical bonds with the honeycomb porous carbon, and the carbon sheets are connected by triangular branched chains, which enhances the structural stability and effectively mitigates the volume expansion of CoP. Based on the excellent structure with triple-doping synergistic effect, the [email protected] anode applied to lithium-ion batteries delivers ultra-high reversible capacity (1237.7 mAh g−1 at 0.5 A g−1) and ultra-long cycle stability at high rates (280.3 and 241.8 mAh g−1 at 5.0 and 10.0 A g−1 after 5000 cycles with no significant capacity decay). This study provides an effective strategy for designing high-performance doped electrode materials." @default.
- W4294927104 created "2022-09-08" @default.
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- W4294927104 date "2022-12-01" @default.
- W4294927104 modified "2023-10-02" @default.
- W4294927104 title "N, P, S triple-doped honeycomb porous carbon multi-dimensionally enhanced CoP for pseudocapacitance-driven high-power lithium storage" @default.
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- W4294927104 doi "https://doi.org/10.1016/j.apsusc.2022.154801" @default.
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