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• W4295078093 abstract "A Water-in-Salt electrolyte solution (WiSE) is a promising aqueous medium for lithium-ion batteries containing highly concentrated electrolytes. For the increased kinetic overpotential of water oxidation in WiSE, the formation of an interfacial layer (IFL) on a positively electrified electrode is crucial. Nonetheless, most related studies have been restricted to theoretical approaches. In this Article, we voltammetrically study the Cl-/Cl3-/Cl2 redox reaction on Pt and glassy carbon (GC) electrodes in WiSE containing LiTFSI (WiSELiTFSI) and demonstrate that careful monitoring of Cl-/Cl3- redox voltammetry can allow recognition of an IFL formed on a positively electrified electrode. The voltammetric wave attributed to the electro-oxidation of Cl- on a GC electrode was negatively more shifted as the molal concentration of LiTFSI was increased from 0.5 to 6 m, while there was no shift on Pt. Also, there was voltammetric resolution into two peaks associated with Cl-/Cl3- and Cl3-/Cl2 on the GC electrode in WiSELiTFSI, while only unresolved, one redox-paired voltammograms were observed on Pt, regardless of the molal concentration of LiTFSI. These two main voltammetric features indicate the LiTFSI-induced IFL coupled with Cl- and Cl3- on a GC electrode induced by an applied potential of ∼2 V versus the point of zero charge (PZC). We found other halide/halogen redox reactions did not show differentiated voltammetric behaviors in WiSELiTFSI, which demonstrates the uniqueness of the Cl-/Cl3- redox reaction for recognizing the IFL formed on a positively charged electrode surface. Lastly, a strong interaction between the IFL and Cl species was also confirmed by XPS measurements." @default.
• W4295078093 created "2022-09-10" @default.
• W4295078093 creator A5026515627 @default.
• W4295078093 creator A5049775642 @default.
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• W4295078093 date "2022-09-08" @default.
• W4295078093 modified "2023-09-23" @default.
• W4295078093 title "Cl^–/Cl₃^– Redox Voltammetry to Recognize the Interfacial Layer on Positively Electrified Carbon in “Water-in-Salt” Electrolytes" @default.
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• W4295078093 doi "https://doi.org/10.1021/acs.analchem.2c02029" @default.
• W4295078093 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36074896" @default.
• W4295078093 hasPublicationYear "2022" @default.
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