FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4295093265> ?p ?o ?g. }

• W4295093265 endingPage "35253" @default.
• W4295093265 startingPage "35241" @default.
• W4295093265 abstract "Designing the core-shell structure and controlling defect engineering are desirable for improving the performance and stability of semiconductor photocatalysts. Herein, CdS nanorods covered with ultra-thin ZnIn 2 S 4 nanosheets, named as CdS@ZnIn 2 S 4 -S V (CdS@ZIS-S V ), was synthesized through the strategy of constructing core-shell structure and regulating vacancies. The core-shell structure can confine Cd 2+ and S 2− locally around CdS instead of rapidly diffusing into the solution, thereby inhibiting photo-corrosion. The abundant S vacancies can capture photogenerated electrons and promote the separation of electron-hole pairs, thereby preventing the oxidation of S 2− by the holes. In addition, Z-Scheme heterojunction structure helps the effective separation of electron-hole pairs. Notably, the hydrogen production rate of CdS@ZIS-S V reached 18.06 mmol g −1 h −1 , which was 16.9 and 19.6 times than pristine CdS (1.16 mmol g −1 h −1 ) and ZIS (0.92 mmol g −1 h −1 ), respectively. Photoelectric Characterization (PEC), Scanning Kelvin Probe (SKP), UV–vis diffuse reflectance spectra (UV–Vis DRS), Finite-Difference Time-Domain (FDTD) explain the electron transfer mechanism and the reason for the enhanced photocatalytic activity. This work has guiding significance for the preparation of photo-catalysts with high activity and inhibiting photo-corrosion by adjusting S vacancies. CdS nanorods covered with ultra-thin ZnIn 2 S 4 nanosheets has been synthesized through the strategy of constructing core-shell structure and regulating vacancies to form the heterojunction of CdS@ZIS with S Vacancies. CdS@ZIS-S V has high photocatalytic activity and excellent stability. UV–Vis, SKP, FDTD simulation and PEC explored the photocatalytic mechanism. • Synthesis of CdS@ZIS core-shell structures containing S vacancies by hydrothermal method. • The core-shell structure and S vacancies can inhibit the photocorrosion of CdS and ZIS, respectively. • The charge carrier transfer between CdS and ZIS follows the Z-scheme route. • CdS@ZIS-Sv exhibits excellent photocatalytic activity and cycling stability." @default.
• W4295093265 created "2022-09-10" @default.
• W4295093265 creator A5000235010 @default.
• W4295093265 creator A5006134706 @default.
• W4295093265 creator A5036794537 @default.
• W4295093265 creator A5039252789 @default.
• W4295093265 creator A5039412958 @default.
• W4295093265 creator A5066207578 @default.
• W4295093265 date "2022-10-01" @default.
• W4295093265 modified "2023-10-12" @default.
• W4295093265 title "In-situ construction of CdS@ZIS Z-scheme heterojunction with core-shell structure: Defect engineering, enhance photocatalytic hydrogen evolution and inhibit photo-corrosion" @default.
• W4295093265 cites W2304399066 @default.
• W4295093265 cites W2604907651 @default.
• W4295093265 cites W2755114261 @default.
• W4295093265 cites W2787309080 @default.
• W4295093265 cites W2787449860 @default.
• W4295093265 cites W2790672850 @default.
• W4295093265 cites W2791953284 @default.
• W4295093265 cites W2799822811 @default.
• W4295093265 cites W2913985424 @default.
• W4295093265 cites W2964732667 @default.
• W4295093265 cites W2967266146 @default.
• W4295093265 cites W3004871517 @default.
• W4295093265 cites W3010559348 @default.
• W4295093265 cites W3047949052 @default.
• W4295093265 cites W3081322132 @default.
• W4295093265 cites W3088305089 @default.
• W4295093265 cites W3094592993 @default.
• W4295093265 cites W3095191114 @default.
• W4295093265 cites W3096880859 @default.
• W4295093265 cites W3097156348 @default.
• W4295093265 cites W3108925529 @default.
• W4295093265 cites W3114930925 @default.
• W4295093265 cites W3120672856 @default.
• W4295093265 cites W3122102290 @default.
• W4295093265 cites W3126696873 @default.
• W4295093265 cites W3134908035 @default.
• W4295093265 cites W3136488625 @default.
• W4295093265 cites W3150887785 @default.
• W4295093265 cites W3155107930 @default.
• W4295093265 cites W3158709488 @default.
• W4295093265 cites W3164592511 @default.
• W4295093265 cites W3166301637 @default.
• W4295093265 cites W3166850252 @default.
• W4295093265 cites W3170937874 @default.
• W4295093265 cites W3175481172 @default.
• W4295093265 cites W3175639566 @default.
• W4295093265 cites W3175800515 @default.
• W4295093265 cites W3179978150 @default.
• W4295093265 cites W3180410763 @default.
• W4295093265 cites W3184695787 @default.
• W4295093265 cites W3185627840 @default.
• W4295093265 cites W3186530899 @default.
• W4295093265 cites W3187923119 @default.
• W4295093265 cites W3195231082 @default.
• W4295093265 cites W3200834547 @default.
• W4295093265 cites W4200413973 @default.
• W4295093265 cites W4205278657 @default.
• W4295093265 cites W4221025255 @default.
• W4295093265 cites W4283399921 @default.
• W4295093265 doi "https://doi.org/10.1016/j.ijhydene.2022.08.129" @default.
• W4295093265 hasPublicationYear "2022" @default.
• W4295093265 type Work @default.
• W4295093265 citedByCount "6" @default.
• W4295093265 countsByYear W42950932652022 @default.
• W4295093265 countsByYear W42950932652023 @default.
• W4295093265 crossrefType "journal-article" @default.
• W4295093265 hasAuthorship W4295093265A5000235010 @default.
• W4295093265 hasAuthorship W4295093265A5006134706 @default.
• W4295093265 hasAuthorship W4295093265A5036794537 @default.
• W4295093265 hasAuthorship W4295093265A5039252789 @default.
• W4295093265 hasAuthorship W4295093265A5039412958 @default.
• W4295093265 hasAuthorship W4295093265A5066207578 @default.
• W4295093265 hasConcept C127413603 @default.
• W4295093265 hasConcept C159985019 @default.
• W4295093265 hasConcept C161790260 @default.
• W4295093265 hasConcept C171250308 @default.
• W4295093265 hasConcept C178790620 @default.
• W4295093265 hasConcept C185592680 @default.
• W4295093265 hasConcept C191897082 @default.
• W4295093265 hasConcept C192562407 @default.
• W4295093265 hasConcept C202189072 @default.
• W4295093265 hasConcept C20625102 @default.
• W4295093265 hasConcept C2164484 @default.
• W4295093265 hasConcept C2777822432 @default.
• W4295093265 hasConcept C2781052500 @default.
• W4295093265 hasConcept C42360764 @default.
• W4295093265 hasConcept C49040817 @default.
• W4295093265 hasConcept C512968161 @default.
• W4295093265 hasConcept C55493867 @default.
• W4295093265 hasConcept C65165184 @default.
• W4295093265 hasConcept C79794668 @default.
• W4295093265 hasConceptScore W4295093265C127413603 @default.
• W4295093265 hasConceptScore W4295093265C159985019 @default.
• W4295093265 hasConceptScore W4295093265C161790260 @default.
• W4295093265 hasConceptScore W4295093265C171250308 @default.
• W4295093265 hasConceptScore W4295093265C178790620 @default.
• W4295093265 hasConceptScore W4295093265C185592680 @default.

• next