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• W4295123320 abstract "Pharmaceutically active compounds (PhACs) are recognized as posing health risks to aquatic ecosystems. The occurrence characteristics and ecological effects of 15 PhACs were investigated in the multiphase media of Yangtze River (Nanjing area, China) during wet and dry seasons. All 15 PhACs were detected in the traditionally dissolved phase, suspended particulate matter, sediment and fish, with total concentrations of PhACs (ΣPhACs) of 64.75–366.20 ng/L, 18.50–69.40 ng/g, 3.29–23.30 ng/g and 0.00–176.44 ng/g, respectively. Ibuprofen (IPF), roxithromycin (ROX) and caffeine (CFI) were the dominant PhACs in all of the environmental media. As the main carrier for PhACs, the colloids contributed 8.60%− 77.04% of PhACs in the traditionally dissolved phase, and distribution coefficients (log Kcol=6.38–7.95) of PhACs in colloidal phase were significantly higher than those in SPM and sediment. The bioaccumulation potential of ΣPhACs in the wild fish tissues was generally in order as follows: brain > liver > kidney > gill > blood > intestines > muscle > bile, which was positively correlated with their log Kow. The concentrations of CFI, ROX and IPF in the muscle, gill and liver can be predicted by their log Kow and pollution levels in the blood, and the concentrations of PhACs in the muscle of benthic fish were much higher than those in pelagic fish. The bioaccumulation factors of ROX, fluoxetine and bezafibrate in intestines, brain and blood showed strong enrichment capacity (>5000). In the risk assessment, the acute risk level of PhACs to aquatic organisms decreases gradually with the trophic level, while the trend of chronic risk was the opposite. The chronic mixture risk of PhACs to fish was > 1 at all sampling sites, 59.79% of mixed risk quotient were provided by clofibric acid, diclofenac, erythromycin and ketoconazole. These results indicated that PhAC can cause harmful health effects to sensitive organisms both individually and mixedly." @default.
• W4295123320 created "2022-09-11" @default.
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• W4295123320 date "2022-10-01" @default.
• W4295123320 modified "2023-10-16" @default.
• W4295123320 title "Pharmaceutically active compounds in biotic and abiotic media of rivers receiving urban sewage: Concentrations, bioaccumulation and ecological risk" @default.
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• W4295123320 doi "https://doi.org/10.1016/j.psep.2022.08.045" @default.
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