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- W4295166004 abstract "A new approach to polysubstituted spiropentanes is developed through a regio- and diastereoselective carbometalation of sp2-disubstituted cyclopropenes. The control of selectivity originates from a combined syn-facial diastereoselective carbometalation with a regio-directed addition. The regio-controlling element subsequently serves as a leaving group in an intramolecular nucleophilic substitution. This method allows the preparation of various polysubstituted spiropentanes with up to five contiguous stereocenters." @default.
- W4295166004 created "2022-09-11" @default.
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- W4295166004 date "2022-09-11" @default.
- W4295166004 modified "2023-09-25" @default.
- W4295166004 title "Stereoselective Synthesis of Polysubstituted Spiropentanes" @default.
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- W4295166004 doi "https://doi.org/10.1021/jacs.2c07370" @default.
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