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- W4295197039 abstract "We report the synthesis of novel terpene-based monomers: nopinyl acrylate and methacrylate, from naturally abundant β-pinene. A very high Tg value was observed for poly(nopinyl methacrylate) when synthesised by free radical polymerisation, and well-defined polymers have been produced via RAFT polymerisation. This exciting new high Tg material shows promise as a hard block in thermoplastic elastomers. ABA triblock copolymers have been synthesised which also incorporate a low Tg renewable soft block, poly(tetrahydrogeraniol methacrylate), using a divergent, difunctional RAFT polymerisation method. Initial phase separation behaviour and adhesive properties have been investigated to highlight the potential of these copolymer materials as renewably sourced thermoplastic elastomers." @default.
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- W4295197039 date "2022-10-01" @default.
- W4295197039 modified "2023-09-27" @default.
- W4295197039 title "Sustainable ABA triblock methacrylate copolymers incorporating both high and low Tg terpene-derived monomers" @default.
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- W4295197039 doi "https://doi.org/10.1016/j.eurpolymj.2022.111567" @default.
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