FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4295213420> ?p ?o ?g. }

• W4295213420 endingPage "154695" @default.
• W4295213420 startingPage "154695" @default.
• W4295213420 abstract "There is an interest in atomic layer deposition as a tool for precise catalyst design and synthesis, due to advantages such as uniform coating, excellent step coverage, and control of thin-film thickness at the atomic level. Using selective atomic layer deposition on platinum-based nanoparticle catalysts improves or maintains catalytic performance, and also improves sintering resistance under high-temperature and -pressure conditions through fine control of the surface. In this study, we used density functional theory to elucidate the mechanism of the initial TiCl4 half-cycle reaction for TiO2 formation on the surface of Pt nanoparticles, and the deposition characteristics according to the crystal properties. In the surface reaction, TiCl4 is adsorbed on Pt (1 1 1), (1 0 0), and (2 1 1) surfaces containing an –OH functional group, and the reaction proceeds through formation of a Pt−O−TiCl3 complex followed by HCl. The chemical adsorption of TiCl4 to the Pt−OH surface has an energy between −2.44 and −2.76 eV, thus providing a highly stable chemical bond. The activation energy of the TiCl4 half-cycle reaction on the surface of Pt nanoparticles is 1.15 – 1.24 eV, in the order Pt (2 1 1) > (1 0 0) > (1 1 1). Via electronic structure analysis of TiCl4-adsorbed Pt nanoparticles, we confirmed that the Pt (1 1 1) surface is a favorable pathway for the release of HCl, enhancing its response to the surface reaction. This study provides a quantitative understanding of the selective atomic layer deposition reaction of the precursor TiCl4 on Pt catalyst surfaces. As theoretical understanding of the deposition process improves, we expect that it will become possible to design precursor materials and process conditions applicable to the specifications required by various industries." @default.
• W4295213420 created "2022-09-12" @default.
• W4295213420 creator A5015901414 @default.
• W4295213420 creator A5049209866 @default.
• W4295213420 creator A5071187682 @default.
• W4295213420 creator A5090980010 @default.
• W4295213420 date "2022-12-01" @default.
• W4295213420 modified "2023-10-14" @default.
• W4295213420 title "Adsorption selectivity of TiCl4 precursor on Pt surfaces for atomic layer deposition via density functional theory" @default.
• W4295213420 cites W1981368803 @default.
• W4295213420 cites W1994403799 @default.
• W4295213420 cites W1995987129 @default.
• W4295213420 cites W2004878979 @default.
• W4295213420 cites W2013288190 @default.
• W4295213420 cites W2029982611 @default.
• W4295213420 cites W2039948490 @default.
• W4295213420 cites W2059885388 @default.
• W4295213420 cites W2084473003 @default.
• W4295213420 cites W2084781518 @default.
• W4295213420 cites W2087585288 @default.
• W4295213420 cites W2105157003 @default.
• W4295213420 cites W2126224336 @default.
• W4295213420 cites W2131606351 @default.
• W4295213420 cites W2149467519 @default.
• W4295213420 cites W2157190313 @default.
• W4295213420 cites W2159752439 @default.
• W4295213420 cites W2184618033 @default.
• W4295213420 cites W2285922596 @default.
• W4295213420 cites W2315641248 @default.
• W4295213420 cites W2328065082 @default.
• W4295213420 cites W2338864617 @default.
• W4295213420 cites W2410011626 @default.
• W4295213420 cites W2522529245 @default.
• W4295213420 cites W2552529400 @default.
• W4295213420 cites W2782082781 @default.
• W4295213420 cites W2795151060 @default.
• W4295213420 cites W2904779592 @default.
• W4295213420 cites W3088281921 @default.
• W4295213420 cites W3175054450 @default.
• W4295213420 cites W3206606417 @default.
• W4295213420 cites W4206818003 @default.
• W4295213420 cites W4220678590 @default.
• W4295213420 doi "https://doi.org/10.1016/j.apsusc.2022.154695" @default.
• W4295213420 hasPublicationYear "2022" @default.
• W4295213420 type Work @default.
• W4295213420 citedByCount "1" @default.
• W4295213420 countsByYear W42952134202023 @default.
• W4295213420 crossrefType "journal-article" @default.
• W4295213420 hasAuthorship W4295213420A5015901414 @default.
• W4295213420 hasAuthorship W4295213420A5049209866 @default.
• W4295213420 hasAuthorship W4295213420A5071187682 @default.
• W4295213420 hasAuthorship W4295213420A5090980010 @default.
• W4295213420 hasConcept C127413603 @default.
• W4295213420 hasConcept C147597530 @default.
• W4295213420 hasConcept C147789679 @default.
• W4295213420 hasConcept C150394285 @default.
• W4295213420 hasConcept C151730666 @default.
• W4295213420 hasConcept C152365726 @default.
• W4295213420 hasConcept C155672457 @default.
• W4295213420 hasConcept C161790260 @default.
• W4295213420 hasConcept C165983687 @default.
• W4295213420 hasConcept C171250308 @default.
• W4295213420 hasConcept C178790620 @default.
• W4295213420 hasConcept C185592680 @default.
• W4295213420 hasConcept C192562407 @default.
• W4295213420 hasConcept C2779227376 @default.
• W4295213420 hasConcept C2816523 @default.
• W4295213420 hasConcept C42360764 @default.
• W4295213420 hasConcept C518104683 @default.
• W4295213420 hasConcept C64297162 @default.
• W4295213420 hasConcept C65024703 @default.
• W4295213420 hasConcept C69544855 @default.
• W4295213420 hasConcept C86803240 @default.
• W4295213420 hasConcept C95121573 @default.
• W4295213420 hasConceptScore W4295213420C127413603 @default.
• W4295213420 hasConceptScore W4295213420C147597530 @default.
• W4295213420 hasConceptScore W4295213420C147789679 @default.
• W4295213420 hasConceptScore W4295213420C150394285 @default.
• W4295213420 hasConceptScore W4295213420C151730666 @default.
• W4295213420 hasConceptScore W4295213420C152365726 @default.
• W4295213420 hasConceptScore W4295213420C155672457 @default.
• W4295213420 hasConceptScore W4295213420C161790260 @default.
• W4295213420 hasConceptScore W4295213420C165983687 @default.
• W4295213420 hasConceptScore W4295213420C171250308 @default.
• W4295213420 hasConceptScore W4295213420C178790620 @default.
• W4295213420 hasConceptScore W4295213420C185592680 @default.
• W4295213420 hasConceptScore W4295213420C192562407 @default.
• W4295213420 hasConceptScore W4295213420C2779227376 @default.
• W4295213420 hasConceptScore W4295213420C2816523 @default.
• W4295213420 hasConceptScore W4295213420C42360764 @default.
• W4295213420 hasConceptScore W4295213420C518104683 @default.
• W4295213420 hasConceptScore W4295213420C64297162 @default.
• W4295213420 hasConceptScore W4295213420C65024703 @default.
• W4295213420 hasConceptScore W4295213420C69544855 @default.
• W4295213420 hasConceptScore W4295213420C86803240 @default.
• W4295213420 hasConceptScore W4295213420C95121573 @default.
• W4295213420 hasLocation W42952134201 @default.
• W4295213420 hasOpenAccess W4295213420 @default.

• next