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• W4295249362 abstract "Postulated in 1992 and synthesized in 2004 above 2000 K and 110 GPa, the singly-bonded nitrogen cubic gauche crystal (cg-PN) is still considered to be the ultimate high energy density material (HEDM). The search however has continued for a method to synthesize cg-PN at more ambient conditions or find HEDMs which can be synthesized at lower pressure and temperature. Here, using ab initio evolutionary crystal prediction techniques, a simpler nitrogen-based molecular crystal consisting of N[Formula: see text] and N[Formula: see text] molecules is revealed to be a more favorable polynitrogen at lower pressures. The energetic gain of 534 meV/atom over cg-PN and 138 meV/atom over the N[Formula: see text] molecular crystal at zero pressure makes the N[Formula: see text]-N[Formula: see text] system more appealing. Dynamical and mechanical stabilities are investigated at 5 and 0 GPa, and vibrational frequencies are assessed for its Raman and IR spectra. The prospects of an experimental synthesis of the N[Formula: see text]-N[Formula: see text] polymeric system compared to cg-PN is higher because the C[Formula: see text] symmetry of N[Formula: see text] within this crystal would be easier to target from the readily available N[Formula: see text] azides and the observed N[Formula: see text] and N[Formula: see text] radicals." @default.
• W4295249362 created "2022-09-12" @default.
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• W4295249362 date "2022-09-12" @default.
• W4295249362 modified "2023-10-14" @default.
• W4295249362 title "A polymeric nitrogen N$$_6$$–N$$_2$$ system with enhanced stability at low pressure" @default.
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• W4295249362 doi "https://doi.org/10.1038/s41598-022-19080-0" @default.
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