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• W4295344512 abstract "In toluene solution, the reaction of [Co2(CO)8] with an equimolar amount of [P(OPh)3] yields first [Co2(CO)7{P(OPh)3}] 1. Following heating of 1, an alternative synthetic access to the tetranuclear cluster [{Co4(μ2-CO)3(CO)8{P(OPh)3}] 2 is provided in a condensation reaction. Compound 2 has been characterized by IR and 31P NMR spectroscopy. The tetranuclear cluster framework has been ascertained by a single-crystal X-ray diffraction study performed at 100 K." @default.
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• W4295344512 date "2022-09-10" @default.
• W4295344512 modified "2023-09-30" @default.
• W4295344512 title "Tris(μ2-carbonyl)octacarbonyl(triphenylphosphite)tetracobalt" @default.
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• W4295344512 doi "https://doi.org/10.3390/m1443" @default.
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