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• W4295786226 abstract "We describe the synthesis, crystallographic characterization of a new Cu-Salphen compound and its use as a host Lewis-acid against guest anions in two versions: a) free molecule, b) copolymerized with methyl methacrylate:n-butyl acrylate (1 : 4-wt.) as protective co-monomers. Higher contents in Cu-Salphen yielded larger and more homogeneous polymer sizes. Polymer size together with glass transitions, heat capacity, thermal degradation, guest-saturation degrees and host-guest species distribution profiles from spectrophotometric titrations explained growths of up to 630-fold in K11 and 180000-fold in K12 for the host's binding site attributable to a solvophobic protection from the macromolecular structure. Spectrofluorimetry revealed blue-shifted×13-16 larger luminescence for Cu-Salphen in the polymers (λem =488-498 nm) than that of the non-polymerized counterpart (λem =510-543 nm) and turn-on blue-shifted enhanced fluorescence upon guest association. We propose a cooperative incorporation of the guests occurring from the outer medium toward internally protected binding site pockets in the random coil polymer conformations." @default.
• W4295786226 created "2022-09-15" @default.
• W4295786226 creator A5005371787 @default.
• W4295786226 creator A5013869771 @default.
• W4295786226 creator A5040547755 @default.
• W4295786226 creator A5048562406 @default.
• W4295786226 creator A5064086119 @default.
• W4295786226 creator A5084465558 @default.
• W4295786226 date "2022-09-29" @default.
• W4295786226 modified "2023-10-15" @default.
• W4295786226 title "Enhanced Host‐Guest Association and Fluorescence in Copolymers from Copper Salphen Complexes by Supramolecular Internalization of Anions" @default.
• W4295786226 cites W1879175808 @default.
• W4295786226 cites W1967020846 @default.
• W4295786226 cites W1969360633 @default.
• W4295786226 cites W1970782191 @default.
• W4295786226 cites W1971670146 @default.
• W4295786226 cites W1976744681 @default.
• W4295786226 cites W1980567381 @default.
• W4295786226 cites W1981366834 @default.
• W4295786226 cites W1982181917 @default.
• W4295786226 cites W1986376909 @default.
• W4295786226 cites W1990170643 @default.
• W4295786226 cites W1992637854 @default.
• W4295786226 cites W1996604440 @default.
• W4295786226 cites W1999292430 @default.
• W4295786226 cites W2000696462 @default.
• W4295786226 cites W2007013745 @default.
• W4295786226 cites W2012301250 @default.
• W4295786226 cites W2012434595 @default.
• W4295786226 cites W2014901496 @default.
• W4295786226 cites W2015300590 @default.
• W4295786226 cites W2026883725 @default.
• W4295786226 cites W2029652115 @default.
• W4295786226 cites W2038412234 @default.
• W4295786226 cites W2040916263 @default.
• W4295786226 cites W2043305897 @default.
• W4295786226 cites W2043781881 @default.
• W4295786226 cites W2045421387 @default.
• W4295786226 cites W2053922811 @default.
• W4295786226 cites W2054510062 @default.
• W4295786226 cites W2056322871 @default.
• W4295786226 cites W2057954591 @default.
• W4295786226 cites W2060124016 @default.
• W4295786226 cites W2072244905 @default.
• W4295786226 cites W2073242396 @default.
• W4295786226 cites W2073732125 @default.
• W4295786226 cites W2078328822 @default.
• W4295786226 cites W2078597449 @default.
• W4295786226 cites W2082454728 @default.
• W4295786226 cites W2091047059 @default.
• W4295786226 cites W2097450943 @default.
• W4295786226 cites W2105165467 @default.
• W4295786226 cites W2109594966 @default.
• W4295786226 cites W2111701836 @default.
• W4295786226 cites W2120321665 @default.
• W4295786226 cites W2120894192 @default.
• W4295786226 cites W2121155250 @default.
• W4295786226 cites W2124145938 @default.
• W4295786226 cites W2132454074 @default.
• W4295786226 cites W2134229410 @default.
• W4295786226 cites W2138927630 @default.
• W4295786226 cites W2139458907 @default.
• W4295786226 cites W2145023151 @default.
• W4295786226 cites W2145738482 @default.
• W4295786226 cites W2146015624 @default.
• W4295786226 cites W2148531683 @default.
• W4295786226 cites W2149031139 @default.
• W4295786226 cites W2150922705 @default.
• W4295786226 cites W2152055606 @default.
• W4295786226 cites W2163541227 @default.
• W4295786226 cites W2177603935 @default.
• W4295786226 cites W2294446746 @default.
• W4295786226 cites W2313327927 @default.
• W4295786226 cites W2313777562 @default.
• W4295786226 cites W2313907546 @default.
• W4295786226 cites W2315537311 @default.
• W4295786226 cites W2317211153 @default.
• W4295786226 cites W2329465416 @default.
• W4295786226 cites W2332260988 @default.
• W4295786226 cites W2335366255 @default.
• W4295786226 cites W2408703191 @default.
• W4295786226 cites W2409865121 @default.
• W4295786226 cites W2466882934 @default.
• W4295786226 cites W2506332640 @default.
• W4295786226 cites W2509060679 @default.
• W4295786226 cites W2512610455 @default.
• W4295786226 cites W2539421382 @default.
• W4295786226 cites W2552173678 @default.
• W4295786226 cites W2563167188 @default.
• W4295786226 cites W2570350533 @default.
• W4295786226 cites W2573528081 @default.
• W4295786226 cites W2586514427 @default.
• W4295786226 cites W2587830577 @default.
• W4295786226 cites W2746202791 @default.
• W4295786226 cites W2773755438 @default.
• W4295786226 cites W2793215502 @default.
• W4295786226 cites W2794950656 @default.
• W4295786226 cites W2795135779 @default.
• W4295786226 cites W2799857395 @default.
• W4295786226 cites W2889284045 @default.

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