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- W4295792014 abstract "The ability to control the composition and structure of inorganic compounds by simple synthesis methods is essential to the design and development of electrode materials of lithium-ion batteries (LIBs). Here we report the controllable synthesis of calcium vanadate micro/nanostructures via a simple hydrothermal method. By easily adjusting the pH value of a reaction system, a Ca10V6O25 straw-bundle-like structure, Ca2V2O7 microplatelet, and CaV6O16·3H2O sponge-like macrostructure can be selectively synthesized. The regulation mechanism of different calcium vanadate micro/nanostructures was investigated. In addition, CaV6O16·3H2O and CaV6O16·3H2O/GO self-standing papers were obtained by pressing the sponge-like macrostructure and vacuum filtration, respectively. The electrochemical performances of the CaV6O16·3H2O and CaV6O16·3H2O/GO papers as the self-standing and binder-free anodes for LIBs were investigated for the first time. The as-obtained CaV6O16·3H2O/GO hybrid paper anode exhibits a high discharge capacity of 664.0 mA h g–1 after 250 cycles at 200 mA g–1 and good cycling stability, demonstrating its potential application as a self-standing anode for LIBs." @default.
- W4295792014 created "2022-09-15" @default.
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- W4295792014 date "2022-09-14" @default.
- W4295792014 modified "2023-10-18" @default.
- W4295792014 title "Calcium Vanadate Micro/Nanostructures for Lithium-Ion Batteries" @default.
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- W4295792014 doi "https://doi.org/10.1021/acsanm.2c02700" @default.
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