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- W4296003086 abstract "Abstract The N ‐dealkylation reactions of benzamides occur naturally in living organisms but chemical methods remain poorly developed. So far, light‐induced variants of these processes have been restricted to amides containing secondary N ‐alkyl groups or required pre‐functionalization of the starting material. Here, we present a direct, controllable N ‐dealkylation of tertiary and secondary benzamides possessing primary alkyl substituents at N ‐atom. The developed strategy operates in aqueous environment under mild conditions involving either blue LEDs or sunlight irradiation. Preliminary mechanistic studies indicate two‐step oxidation and the intermediacy of radicals at α‐position to N ‐atom. Selectivity in N ‐dealkylation of homo‐ and heterosubstituted tertiary benzamides is also investigated." @default.
- W4296003086 created "2022-09-16" @default.
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- W4296003086 date "2022-10-05" @default.
- W4296003086 modified "2023-09-26" @default.
- W4296003086 title "Light‐Induced Dealkylation of Benzamides in Aqueous Solution" @default.
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- W4296003086 doi "https://doi.org/10.1002/ejoc.202200913" @default.
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