Matches in SemOpenAlex for { <https://semopenalex.org/work/W4296089700> ?p ?o ?g. }
Showing items 1 to 34 of
34
with 100 items per page.
- W4296089700 abstract "Both natural biomaterials and synthetic materials benefit from complex energy landscapes that provide the foundation for structure-function relationships and environmental sensitivity. Understanding these nonequilibrium dynamics is important for the development of design principles to harness this behavior. Using a model system of poly(ethylene glycol) methacrylate-based lower critical solution temperature (LCST) copolymers, we explored the impact of composition, path, and macromolecular crowding effects on nonequilibrium thermal hysteretic behavior. Through turbidimetry analysis of non-superimposable heat-cool cycles, we observe that LCST copolymers show clear hysteresis that varies as a function of pendent side chain length and hydrophobicity. Hysteresis is further impacted by the temperature ramp rate, as insoluble states can be kinetically trapped under optimized temperature protocols. Finally, the use of common crowding agents shows that excluded volume effects diminish the hysteresis behavior. This systematic study brings to light practical design principles towards understanding and harnessing out-of-equilibrium effects in synthetic soft materials." @default.
- W4296089700 created "2022-09-17" @default.
- W4296089700 creator A5010195063 @default.
- W4296089700 creator A5055747959 @default.
- W4296089700 creator A5091049741 @default.
- W4296089700 date "2022-09-15" @default.
- W4296089700 modified "2023-09-30" @default.
- W4296089700 title "Temperature sensitive copolymers as a model system for understanding the physical basis of nonequilibrium assembly" @default.
- W4296089700 doi "https://doi.org/10.26434/chemrxiv-2022-77cdd" @default.
- W4296089700 hasPublicationYear "2022" @default.
- W4296089700 type Work @default.
- W4296089700 citedByCount "0" @default.
- W4296089700 crossrefType "posted-content" @default.
- W4296089700 hasAuthorship W4296089700A5010195063 @default.
- W4296089700 hasAuthorship W4296089700A5055747959 @default.
- W4296089700 hasAuthorship W4296089700A5091049741 @default.
- W4296089700 hasBestOaLocation W42960897001 @default.
- W4296089700 hasFunder F4320337480 @default.
- W4296089700 hasLocation W42960897001 @default.
- W4296089700 hasOpenAccess W4296089700 @default.
- W4296089700 hasPrimaryLocation W42960897001 @default.
- W4296089700 hasRelatedWork W1808537114 @default.
- W4296089700 hasRelatedWork W1978834329 @default.
- W4296089700 hasRelatedWork W1987336599 @default.
- W4296089700 hasRelatedWork W2040892511 @default.
- W4296089700 hasRelatedWork W2055345491 @default.
- W4296089700 hasRelatedWork W2082949374 @default.
- W4296089700 hasRelatedWork W2315111237 @default.
- W4296089700 hasRelatedWork W2376233740 @default.
- W4296089700 hasRelatedWork W2387819216 @default.
- W4296089700 hasRelatedWork W2808458951 @default.
- W4296089700 isParatext "false" @default.
- W4296089700 isRetracted "false" @default.
- W4296089700 workType "article" @default.