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• W4296180613 startingPage "123936" @default.
• W4296180613 abstract "This work describes a molecularly imprinted (MIP) sensor, based on the electropolymerization of pyrrole on a glassy carbon electrode (GCE), for the determination of ethanethiol. Ethanethiol was used as a template molecule for the formation of cavities in the imprinted polymer. The effect of molar ratios template molecules/functional monomers and time needed to remove the template were optimized. The developed MIP/GCE sensor presented a linear range from 6.1 to 32.4 mg L-1 with capability detection and reproducibility values of 7.2 mg L-1 and 10.4%, respectively. The sensitivity of the developed sensor was enhanced by the incorporation of gold nanoparticles (AuNPs). The AuNPs/MIP/GCE showed a capability of detection and reproducibility values of 0.4 mg L-1 and 4.1%, respectively (calibration range from 0.3 to 3.1 mg L-1). The sensor was successfully applied to the determination of ethanethiol in spiked wine samples with recoveries ranging from 99% to 107%." @default.
• W4296180613 created "2022-09-18" @default.
• W4296180613 creator A5036413286 @default.
• W4296180613 creator A5061665868 @default.
• W4296180613 date "2023-02-01" @default.
• W4296180613 modified "2023-10-14" @default.
• W4296180613 title "Molecularly imprinted polypyrrole based electrochemical sensor for selective determination of ethanethiol" @default.
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• W4296180613 doi "https://doi.org/10.1016/j.talanta.2022.123936" @default.
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